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College of Engineering(공과대학)Dept. of Nuclear and Quantum Engineering(원자력및양자공학과)NE-Journal Papers(저널논문)

Kinetic Studies of Intramolecular Additions of Alkyl Radicals onto Imines

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dc.contributor.authorKim, Sung Gakko
dc.contributor.author윤광섭ko
dc.contributor.author김용석ko
dc.date.accessioned2013-02-27T14:57:10Z-
dc.date.available2013-02-27T14:57:10Z-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued1997-01-
dc.identifier.citationTETRAHEDRON, v.53, no.1, pp.73 - 80-
dc.identifier.issn0040-4020-
dc.identifier.urihttp://hdl.handle.net/10203/69201-
dc.description.abstractThe approximate rate constants for 5-exo and 6-exo cyclizations of alkyl radicals onto imines have been kinetically determined to be 6.0x10(6) s(-1) and 6.7x10(5) s(-1) at 80 degrees C, respectively. Alkyl radical additions to imines were essentially irreversible and considerably slower than alkyl radical additions to hydrazones. Copyright (C) 1996 Elsevier Science Ltd-
dc.languageEnglish-
dc.publisherPergamon-Elsevier Science Ltd-
dc.subjectN-AZIRIDINYL IMINES-
dc.subjectOMEGA-FORMYLALKYL RADICALS-
dc.subjectNORMAL-BUTYLTIN HYDRIDE-
dc.subjectRING EXPANSION-
dc.subjectRATE CONSTANTS-
dc.subjectOXIME ETHERS-
dc.subjectFUSED CYCLOBUTANONES-
dc.subjectORGANIC-SYNTHESIS-
dc.subjectCHAIN REACTIONS-
dc.subjectCYCLIZATION-
dc.titleKinetic Studies of Intramolecular Additions of Alkyl Radicals onto Imines-
dc.typeArticle-
dc.identifier.wosidA1997VY37300006-
dc.identifier.scopusid2-s2.0-0031060233-
dc.type.rimsART-
dc.citation.volume53-
dc.citation.issue1-
dc.citation.beginningpage73-
dc.citation.endingpage80-
dc.citation.publicationnameTETRAHEDRON-
dc.contributor.localauthorKim, Sung Gak-
dc.contributor.nonIdAuthor윤광섭-
dc.contributor.nonIdAuthor김용석-
dc.type.journalArticleArticle-
dc.subject.keywordPlusN-AZIRIDINYL IMINES-
dc.subject.keywordPlusOMEGA-FORMYLALKYL RADICALS-
dc.subject.keywordPlusNORMAL-BUTYLTIN HYDRIDE-
dc.subject.keywordPlusRING EXPANSION-
dc.subject.keywordPlusRATE CONSTANTS-
dc.subject.keywordPlusOXIME ETHERS-
dc.subject.keywordPlusFUSED CYCLOBUTANONES-
dc.subject.keywordPlusORGANIC-SYNTHESIS-
dc.subject.keywordPlusCHAIN REACTIONS-
dc.subject.keywordPlusCYCLIZATION-
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