Oxidative decarboxylation of arylacetic acids mediated by peroxysulfur intermediate generated from 2-nitrobenzenesulfonyl chloride and superoxide
The oxidative decarboxylation of aryl, alpha,alpha-diaryl, or arylalkylacetic acids has been achieved by a 2-nitrobenzenesulfonyl peroxy radical intermediate (I) generated by the reaction of 2-nitrobenzenesulfonyl chloride with potassium superoxide at -20 degrees C in dry acetonitrile. (C) 1998 Elsevier Science Ltd. All rights reserved.
- Publisher
- PERGAMON-ELSEVIER SCIENCE LTD
- Issue Date
- 1998-02
- Language
- English
- Article Type
- Article
- Keywords
AROMATIC HYDROXYLATION; SYNTHETIC REACTIONS; PEROXYDISULFATE; MECHANISM; ANION
- Citation
TETRAHEDRON LETTERS, v.39, no.7, pp.639 - 642
- ISSN
- 0040-4039
- Appears in Collection
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