A facile deamination of aziridines using N2O4 under very mild conditions

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Various aziridines reacted with N2O4 (2 eq) in the presence of Et3N ( 1 or 2 eq) in dry THF to give the corresponding ethylenes in good to excellent yields at (-23 degrees C or -43 degrees C) in 10 min under Ar.
Publisher
MARCEL DEKKER INC
Issue Date
1999
Language
English
Article Type
Article
Keywords

DINITROGEN TETROXIDE; PYRROLIZIDINE ALKALOIDS; CONVERSION; DERIVATIVES; EXPANSION; AZIDES; ACIDS

Citation

SYNTHETIC COMMUNICATIONS, v.29, no.7, pp.1241 - 1248

ISSN
0039-7911
DOI
10.1080/00397919908086096
URI
http://hdl.handle.net/10203/67697
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