A facile construction of the quadranoid skeleton: Application to the total synthesis of (+/-)-suberosenone

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A tandem free radical cyclization-rearrangement sequence was designed and executed to produce tricyclo[4.3.2.0(1,5)]undecane 7 from cyclopentene 6A in a single operation. The total synthesis of suberosenone was accomplished from 7.
Publisher
AMER CHEMICAL SOC
Issue Date
2000-06
Language
English
Article Type
Article
Keywords

ORGANOSELENIUM CHEMISTRY; ORGANIC-SYNTHESIS; QUADRONE; KETONES; REARRANGEMENT; SUBEROSENONE; RADICALS; ALCOHOLS

Citation

ORGANIC LETTERS, v.2, no.13, pp.1951 - 1953

ISSN
1523-7060
DOI
10.1021/ol0060230
URI
http://hdl.handle.net/10203/67696
Appears in Collection
CH-Journal Papers(저널논문)
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