Mercurinium Ion Mediated Ring Expansion of 1-Alkenyl-1-cycloalkanols

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TMS ethers of 1-alkenyl-1-cycloalkanols readily rearranged to the ring expanded beta-mercurio cycloalkanones via mercurinium ions, which could be converted into alpha-methylene cycloalkanones through elimination and further one carbon expanded cycloalkanones via free radical chain reactions.
Publisher
Pergamon-Elsevier Science Ltd
Issue Date
1992-07
Language
English
Article Type
Article
Keywords

REARRANGEMENT; KETONES; CYCLOPENTYNE; RADICALS

Citation

TETRAHEDRON LETTERS, v.33, no.30, pp.4325 - 4328

ISSN
0040-4039
URI
http://hdl.handle.net/10203/64312
Appears in Collection
CH-Journal Papers(저널논문)
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