ENANTIOSELECTIVE EPOXIDATION OF CYCLIC 1,3-DIENES CATALYZED BY A STERICALLY AND ELECTRONICALLY OPTIMIZED (SALEN)MN COMPLEX
Chiral (salen)Mn(m)Cl complexes catalyze epoxidation of cyclic 1,3-dienes with moderate-to-good enantioselectivity. A new catalyst (2), bearing sterically hindered and electron donating OSi(iPr)(3) (OTIPS)substituents, induces up to 12% higher selectivity than the previously-reported tert-butyl substituted analog 1.
- Publisher
- PERGAMON-ELSEVIER SCIENCE LTD
- Issue Date
- 1994-01
- Language
- English
- Article Type
- Article
- Keywords
EPOXIDES
- Citation
TETRAHEDRON LETTERS, v.35, no.5, pp.669 - 672
- ISSN
- 0040-4039
- Appears in Collection
- CH-Journal Papers(저널논문)
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