A HIGHLY CONDUCTIVE AND CRYSTALLINE GRAPHITE-LIKE POLYMER FROM 2,4-HEXADIYN-1,6-DIOL

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Poly-(2,4-hexadiyn-1,6-diol) (PHDO), prepared by NbCl5/(n-Bu)(4)Sn catalyzed metathesis of HDO, was pyrolyzed at various temperatures and electrical and structural properties of resulting polymers were investigated by FT-IR, Laser Raman, CP/MAS C-13-NMR and Xray diffraction methods. The polymer obtained by pyrolysis of PHDO at 800 degrees C showed a conductivity of about 10 S/cm at room temperature. The structure of the polymer seems to be a graphite-like crystal consisting of condensed aromatic layers. (C) 1994 John Wiley & Sons, Inc.
Publisher
JOHN WILEY SONS INC
Issue Date
1994-10
Language
English
Article Type
Article
Keywords

SOLID-STATE POLYMERIZATION; POLYACETYLENE; POLYACENE

Citation

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, v.32, no.13, pp.2437 - 2441

ISSN
0887-624X
DOI
10.1002/pola.1994.080321305
URI
http://hdl.handle.net/10203/55833
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