Synthesis and characterization of group 4 constrained geometry complexes containing a linked cyclopentadienyl-o-carboranyl ligand
Novel linked cyclopentadienyl-o-carboranyl group 4 metal complexes, [eta (5):eta (1)-Me2Si(C5Me4)(C2B10H10]TiCl2 (2) and [eta (5):eta (1)-Me2Si(C5Me4)(C2B10H10)]Zr(NMe2)(2) (3), have been prepared via salt metathesis and amine elimination. reactions utilizing the linked o-carboranyl ligand, Me2Si(C5Me4H)(C2B10H11) (1). Their X-ray crystal structures are reported.
- Publisher
- AMER CHEMICAL SOC
- Issue Date
- 2000-12
- Language
- English
- Article Type
- Article
- Keywords
OLEFIN POLYMERIZATION CATALYSIS; STRUCTURAL CHARACTERIZATION; MOLECULAR-STRUCTURE; ORGANOLANTHANIDE COMPLEXES; ETHYLENE POLYMERIZATION; ZIRCONIUM COMPLEXES; EFFICIENT SYNTHESIS; AMINE ELIMINATION; VERSATILE LIGAND; AMIDO CATALYSTS
- Citation
ORGANOMETALLICS, v.19, no.25, pp.5514 - 5517
- ISSN
- 0276-7333
- Appears in Collection
- CH-Journal Papers(저널논문)
- Files in This Item
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