DC Field | Value | Language |
---|---|---|
dc.contributor.author | Ihm, Son Ki | ko |
dc.date.accessioned | 2008-04-01T08:59:02Z | - |
dc.date.available | 2008-04-01T08:59:02Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 2003-12 | - |
dc.identifier.citation | CATALYSIS COMMUNICATIONS, v.4, no.12, pp.615 - 619 | - |
dc.identifier.issn | 1566-7367 | - |
dc.identifier.uri | http://hdl.handle.net/10203/3607 | - |
dc.description.abstract | The boron trifluoride etherate, BF3OEt2, was used as an activator towards bis(acetylacetonate)palladium precursor in the polymerization of norbornene. The catalyst system Pd(Acac)(2)/BF3OEt2 was highly active in the polymerization of norbornene. Catalytic activity up to 20,220 kg/(mol Pd (.) h) and intrinsic viscosities up to 2.64 dL/g were observed, respectively. Catalytic activity, polymer yield and polymer molecular weight could be controlled by varying the reaction parameters. The molar mass distribution indicates a single-site, highly homogeneous character of the active catalyst species. NMR spectroscopy study of the polymer showed exclusively 2,7-enchained repeating units of polymer backbone. (C) 2003 Elsevier B.V. All rights reserved. | - |
dc.language.iso | en_US | en |
dc.publisher | Elsevier Science Bv | - |
dc.subject | VINYL POLYMERIZATION | - |
dc.subject | METAL-CATALYSTS | - |
dc.subject | HOMOPOLYMERIZATION | - |
dc.subject | COPOLYMERIZATION | - |
dc.subject | MONOMER | - |
dc.subject | STYRENE | - |
dc.title | Novel bis(acetylacetonate)palladium/boron trifluoride etherate catalyst system for the polymerization of norbornene | - |
dc.type | Article | - |
dc.identifier.wosid | 000187462300002 | - |
dc.identifier.scopusid | 2-s2.0-1642382633 | - |
dc.type.rims | ART | - |
dc.citation.volume | 4 | - |
dc.citation.issue | 12 | - |
dc.citation.beginningpage | 615 | - |
dc.citation.endingpage | 619 | - |
dc.citation.publicationname | CATALYSIS COMMUNICATIONS | - |
dc.embargo.liftdate | 9999-12-31 | - |
dc.embargo.terms | 9999-12-31 | - |
dc.contributor.localauthor | Ihm, Son Ki | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | boron trifluoride | - |
dc.subject.keywordAuthor | cocatalyst | - |
dc.subject.keywordAuthor | norbomene | - |
dc.subject.keywordAuthor | palladium | - |
dc.subject.keywordAuthor | polymerization | - |
dc.subject.keywordPlus | VINYL POLYMERIZATION | - |
dc.subject.keywordPlus | METAL-CATALYSTS | - |
dc.subject.keywordPlus | HOMOPOLYMERIZATION | - |
dc.subject.keywordPlus | COPOLYMERIZATION | - |
dc.subject.keywordPlus | MONOMER | - |
dc.subject.keywordPlus | STYRENE | - |
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