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College of Engineering(공과대학)Dept. of Chemical and Biomolecular Engineering(생명화학공학과)CBE-Journal Papers(저널논문)

Novel monodentate phosphine modified Pd(acac)(2)/BF3OEt2 catalyst system for the synthesis of poly(5-alkyl-2-norbornene)s

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dc.contributor.authorMyagmarsuren, Gko
dc.contributor.authorLee, KSko
dc.contributor.authorJeong, OYko
dc.contributor.authorIhm, Son Kiko
dc.date.accessioned2008-03-31T06:43:10Z-
dc.date.available2008-03-31T06:43:10Z-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued2005-
dc.identifier.citationCATALYSIS COMMUNICATIONS, v.6, no.5, pp.337 - 342-
dc.identifier.issn1566-7367-
dc.identifier.urihttp://hdl.handle.net/10203/3600-
dc.description.abstractPd(acac)(2) + 2PPh(3) + 25BF(3)OEt(2) catalyst system has been employed for the polymerization of 5-alkyl-2-norbornenes. The activity of the catalyst system is comparable to that of most active late transition metal catalysts described in the literature. The introduction of a phosphine to the system switched the carbocationic polymerization mechanism to the coordination Ziegler-Natta polymerization. © 2005 Elsevier B.V. All rights reserved.-
dc.languageEnglish-
dc.language.isoen_USen
dc.publisherElsevier Science Bv-
dc.subjectIN-SITU FORMATION-
dc.subjectADDITION POLYMERIZATION-
dc.subjectNORBORNENE DERIVATIVES-
dc.subjectVINYL-POLYMERIZATION-
dc.subjectFUNCTIONAL-GROUPS-
dc.subjectMETAL-CATALYSTS-
dc.subjectPRE-CATALYSTS-
dc.subjectCOMPLEXES-
dc.subjectHOMOPOLYMERIZATION-
dc.subjectCOPOLYMERIZATION-
dc.titleNovel monodentate phosphine modified Pd(acac)(2)/BF3OEt2 catalyst system for the synthesis of poly(5-alkyl-2-norbornene)s-
dc.typeArticle-
dc.identifier.wosid000228936300004-
dc.identifier.scopusid2-s2.0-25144511821-
dc.type.rimsART-
dc.citation.volume6-
dc.citation.issue5-
dc.citation.beginningpage337-
dc.citation.endingpage342-
dc.citation.publicationnameCATALYSIS COMMUNICATIONS-
dc.identifier.doi10.1016/j.catcom.2005.02.007-
dc.embargo.liftdate9999-12-31-
dc.embargo.terms9999-12-31-
dc.contributor.localauthorIhm, Son Ki-
dc.contributor.nonIdAuthorMyagmarsuren, G-
dc.contributor.nonIdAuthorLee, KS-
dc.contributor.nonIdAuthorJeong, OY-
dc.type.journalArticleArticle-
dc.subject.keywordAuthoralkylnorbornene-
dc.subject.keywordAuthorpalladium-
dc.subject.keywordAuthorpolymerization-
dc.subject.keywordAuthortriphenylphosphine-
dc.subject.keywordPlusIN-SITU FORMATION-
dc.subject.keywordPlusADDITION POLYMERIZATION-
dc.subject.keywordPlusNORBORNENE DERIVATIVES-
dc.subject.keywordPlusVINYL-POLYMERIZATION-
dc.subject.keywordPlusFUNCTIONAL-GROUPS-
dc.subject.keywordPlusMETAL-CATALYSTS-
dc.subject.keywordPlusPRE-CATALYSTS-
dc.subject.keywordPlusCOMPLEXES-
dc.subject.keywordPlusHOMOPOLYMERIZATION-
dc.subject.keywordPlusCOPOLYMERIZATION-
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