DC Field | Value | Language |
---|---|---|
dc.contributor.advisor | Lee, Hee-Yoon | - |
dc.contributor.advisor | 이희윤 | - |
dc.contributor.author | Kim, Byung-Gyu | - |
dc.contributor.author | 김병규 | - |
dc.date.accessioned | 2011-12-13T05:01:11Z | - |
dc.date.available | 2011-12-13T05:01:11Z | - |
dc.date.issued | 1997 | - |
dc.identifier.uri | http://library.kaist.ac.kr/search/detail/view.do?bibCtrlNo=112774&flag=dissertation | - |
dc.identifier.uri | http://hdl.handle.net/10203/32754 | - |
dc.description | 학위논문(석사) - 한국과학기술원 : 화학과, 1997.2, [ iii, 67 p. ] | - |
dc.description.abstract | The radical cyclization and the rearrangement of model compound 2 were studied. Enyne 2 under radical cyclization condition gave a mixture of 5-exo product and the rearranged 6-endo product. As the concentration of $Bu_3SnH$ was diluted, the ratio of 6-endo product to 5-exo product increased. Substituents at $C_1$ and $C_2$ is important for the radical rearrangement. When various hydride sources ($Ph_3GeH, (TMS)_3SiH$ and $PhSH$) are used, the similar kinetic results were obtained. Also, stabilization the radical intermediate by these groups is important for the rearrangement. Tricyclo[4.3.2.0 1,5]undecane ring system was synthesized through tandem radical reaction sequence which involved the rearrangement. Several dienynes and endiynes under radical cyclization uniformly produced the tricyclic compounds. This tandem radical reaction would be applied to the synthesis of the natural products. | eng |
dc.language | eng | - |
dc.publisher | 한국과학기술원 | - |
dc.subject | Rearrangement | - |
dc.subject | Free radicals | - |
dc.subject | Tricyclo[4,3,2,0 1,5]undecane ring system | - |
dc.subject | Synthesis | - |
dc.subject | Application | - |
dc.title | Studies on the rearrangement of free radicals and its application to the synthesis of tricyclo[4.3.2.0 1,5]undecane ring system | - |
dc.title.alternative | 자유 라디칼의 전이 반응에 관한 연구와 세고리 화합물의 합성에의 응용에 관한 연구 | - |
dc.type | Thesis(Master) | - |
dc.identifier.CNRN | 112774/325007 | - |
dc.description.department | 한국과학기술원 : 화학과, | - |
dc.identifier.uid | 000953061 | - |
dc.contributor.localauthor | Lee, Hee-Yoon | - |
dc.contributor.localauthor | 이희윤 | - |
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