DC Field | Value | Language |
---|---|---|
dc.contributor.advisor | Kim, Yong-Hae | - |
dc.contributor.advisor | 김용해 | - |
dc.contributor.author | Choi, Jun-Young | - |
dc.contributor.author | 최준영 | - |
dc.date.accessioned | 2011-12-13T05:00:09Z | - |
dc.date.available | 2011-12-13T05:00:09Z | - |
dc.date.issued | 1994 | - |
dc.identifier.uri | http://library.kaist.ac.kr/search/detail/view.do?bibCtrlNo=69199&flag=dissertation | - |
dc.identifier.uri | http://hdl.handle.net/10203/32686 | - |
dc.description | 학위논문(석사) - 한국과학기술원 : 화학과, 1994.2, [ v, 43 p. ] | - |
dc.description.abstract | The stereocontrolled addition of organometallics to carbonyl compounds possessing chiral auxiliary is a highly useful synthetic operation for the asymmetric synthesis. Diastereoselective addition of several organometallics to the chiral $\alpha$-ketoamides, prepared from $\alpha$-keto acid and new chiral (S)-2-methoxymethylindoline, afforded optically active $\alpha$-hydroxy amides. Organotitanium reagents resulted in best results up to $>96\%$ de. The ratio of diastereomers was determined by the chiral column (CHIRAL CELL OD) chromatography and $^1H$ NMR analysis (300 MHz). | eng |
dc.language | eng | - |
dc.publisher | 한국과학기술원 | - |
dc.title | Stereoselective addition reaction of organometallics to α-keto amides having (S)-2-methoxymethylindoline | - |
dc.title.alternative | (S)-2-메톡시메틸인돌린을 포함하고 있는 키랄 α-케토 아미드에 유기금속물들의 입체선택적 첨가반응 | - |
dc.type | Thesis(Master) | - |
dc.identifier.CNRN | 69199/325007 | - |
dc.description.department | 한국과학기술원 : 화학과, | - |
dc.identifier.uid | 000923543 | - |
dc.contributor.localauthor | Kim, Yong-Hae | - |
dc.contributor.localauthor | 김용해 | - |
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