Recombination of methyl radical at 121.6nm121.6nm 에서 메틸 라디칼의 recombination에 관한 연구

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dc.contributor.advisorJung, Kyung-Hoon-
dc.contributor.advisor정경훈-
dc.contributor.authorYi, Hun-Jung-
dc.contributor.author이헌정-
dc.date.accessioned2011-12-13T04:58:59Z-
dc.date.available2011-12-13T04:58:59Z-
dc.date.issued1991-
dc.identifier.urihttp://library.kaist.ac.kr/search/detail/view.do?bibCtrlNo=67637&flag=dissertation-
dc.identifier.urihttp://hdl.handle.net/10203/32607-
dc.description학위논문(석사) - 한국과학기술원 : 화학과, 1991.2, [ iv, 39 p. ]-
dc.description.abstractA vacuum ultraviolet photolysis of methyl bromide at 121.6nm(253.1kal/mol) by using the hydrogen resonance lamp was studied over the pressure range of 1-50 Torr at room temperature. The result demonstrate the two decomposition mode, i.e., the molecular elimination of HBr to frommethylene, and the C-Br bond cleavage to form methyl radical. The major products of the reaction were found to be $CH_4$, $C_2H_4$, and $C_2H_6$. The branching ratios between the molecular elimination and the methyl radical formation were 0.05:0.95. The scavenger effect was studued by adding HBr as a radical capture to obtain information about primary process. The pressure was also observed by adding inert gases, i.e., $N_2$ and He.eng
dc.languageeng-
dc.publisher한국과학기술원-
dc.titleRecombination of methyl radical at 121.6nm-
dc.title.alternative121.6nm 에서 메틸 라디칼의 recombination에 관한 연구-
dc.typeThesis(Master)-
dc.identifier.CNRN67637/325007-
dc.description.department한국과학기술원 : 화학과, -
dc.identifier.uid000891409-
dc.contributor.localauthorJung, Kyung-Hoon-
dc.contributor.localauthor정경훈-
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CH-Theses_Master(석사논문)
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