DC Field | Value | Language |
---|---|---|
dc.contributor.author | Han, Junghun | ko |
dc.contributor.author | Lee, Michael J. | ko |
dc.contributor.author | Min, Ju Hong | ko |
dc.contributor.author | Kim, Keun Hee | ko |
dc.contributor.author | Lee, Kyungbin | ko |
dc.contributor.author | Kwon, Seung Ho | ko |
dc.contributor.author | Park, Jinseok | ko |
dc.contributor.author | Ryu, Kun | ko |
dc.contributor.author | Seong, Hyeonseok | ko |
dc.contributor.author | Kang, Hyewon | ko |
dc.contributor.author | Lee, Eunji | ko |
dc.contributor.author | Lee, Seung Woo | ko |
dc.contributor.author | Kim, Bumjoon J. | ko |
dc.date.accessioned | 2024-09-05T11:00:15Z | - |
dc.date.available | 2024-09-05T11:00:15Z | - |
dc.date.created | 2024-01-03 | - |
dc.date.issued | 2024-05 | - |
dc.identifier.citation | ADVANCED FUNCTIONAL MATERIALS, v.34, no.19 | - |
dc.identifier.issn | 1616-301X | - |
dc.identifier.uri | http://hdl.handle.net/10203/322724 | - |
dc.description.abstract | Solid-state lithium (Li) metal batteries (LMBs) have been developed as a promising replacement for conventional Li-ion batteries due to their potential for higher energy. However, the current solid-state electrolytes used in LMBs have limitations regarding mechanical and electrochemical properties and interfacial stability. Here, a fluorine (F)-containing solid polymer electrolyte (SPE) having a bi-continuous structure of F-containing elastomers and plastic crystals is reported. The trifluoroethyl acrylate-based SPE (T-SPE) exhibits high ionic conductivity over 10-3 S cm-1, superior mechanical elasticity, and robust LiF-rich interphases at both the Li metal anode and the LiNi0.83Mn0.06Co0.11O2 cathode. Full cells with thin T-SPEs and low negative/positive capacity ratios below 0.5 at the high-operating voltage of 4.5 V demonstrate a high specific energy of 538 Wh kganode+cathode+electrolyte-1 and maintain 393 Wh kg-1 at a high specific power of 804 W kganode+cathode+electrolyte-1. The F-containing phase-separated SPE system provides a powerful strategy for achieving high-energy and -power solid-state LMBs.,The fluorine (F)-containing solid polymer electrolyte (SPE) having a bicontinuous structure of F-containing elastomers and plastic crystals exhibits an unparalleled combination of high ionic conductivity, mechanical elasticity, and robust interfacial properties for achieving high-energy and -power solid state Li metal batteries.image, | - |
dc.language | English | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | Fluorine-Containing Phase-Separated Polymer Electrolytes Enabling High-Energy Solid-State Lithium Metal Batteries | - |
dc.type | Article | - |
dc.identifier.wosid | 001139616000001 | - |
dc.identifier.scopusid | 2-s2.0-85181883330 | - |
dc.type.rims | ART | - |
dc.citation.volume | 34 | - |
dc.citation.issue | 19 | - |
dc.citation.publicationname | ADVANCED FUNCTIONAL MATERIALS | - |
dc.identifier.doi | 10.1002/adfm.202310801 | - |
dc.contributor.localauthor | Kim, Bumjoon J. | - |
dc.contributor.nonIdAuthor | Han, Junghun | - |
dc.contributor.nonIdAuthor | Lee, Michael J. | - |
dc.contributor.nonIdAuthor | Min, Ju Hong | - |
dc.contributor.nonIdAuthor | Kim, Keun Hee | - |
dc.contributor.nonIdAuthor | Lee, Kyungbin | - |
dc.contributor.nonIdAuthor | Kwon, Seung Ho | - |
dc.contributor.nonIdAuthor | Park, Jinseok | - |
dc.contributor.nonIdAuthor | Ryu, Kun | - |
dc.contributor.nonIdAuthor | Seong, Hyeonseok | - |
dc.contributor.nonIdAuthor | Kang, Hyewon | - |
dc.contributor.nonIdAuthor | Lee, Eunji | - |
dc.contributor.nonIdAuthor | Lee, Seung Woo | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | fluorine-containing polymer electrolyte | - |
dc.subject.keywordAuthor | high-energy-density | - |
dc.subject.keywordAuthor | lithium-metal batteries | - |
dc.subject.keywordAuthor | phase-separated structure | - |
dc.subject.keywordAuthor | solid-state electrolyte | - |
dc.subject.keywordPlus | ION-TRANSPORT | - |
dc.subject.keywordPlus | CONDUCTIVITY | - |
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