DC Field | Value | Language |
---|---|---|
dc.contributor.author | Lee, Gi Woo | ko |
dc.contributor.author | Ahn, Hyeon Geun | ko |
dc.contributor.author | Kim, Tae Kyu | ko |
dc.contributor.author | Lee, Sang Kuk | ko |
dc.date.accessioned | 2024-03-06T03:00:28Z | - |
dc.date.available | 2024-03-06T03:00:28Z | - |
dc.date.created | 2024-02-28 | - |
dc.date.issued | 2007-10 | - |
dc.identifier.citation | CHEMICAL PHYSICS LETTERS, v.447, no.4-6, pp.197 - 201 | - |
dc.identifier.issn | 0009-2614 | - |
dc.identifier.uri | http://hdl.handle.net/10203/318432 | - |
dc.description.abstract | We report the spectroscopic observation of difluorobenzyl radical in a corona excited supersonic expansion using a pinhole-type glass nozzle. A jet-cooled 2,3-difluorobenzyl radical was generated and vibronically excited from 2,3-difluorotoluene seeded in a large amount of inert carrier gas He. The vibronic emission spectra of the jet-cooled 2,3-difluorobenzyl radical were recorded for the first time in the visible region and analyzed to obtain an accurate measurement of the vibronic transition energy between the D-1 and D-0 electronic states. The vibrational mode frequencies in the ground electronic state were determined by comparison with those from an ab initio calculation as well as those of 2,6-difluorobenzyl radical and 1,2,3-trimethylbenzene. (C) 2007 Elsevier B.V. All rights reserved. | - |
dc.language | English | - |
dc.publisher | ELSEVIER SCIENCE BV | - |
dc.title | Vibronic emission spectra of jet-cooled 2,3-difluorobenzyl radical in a corona excited supersonic expansion | - |
dc.type | Article | - |
dc.identifier.wosid | 000250911700004 | - |
dc.identifier.scopusid | 2-s2.0-35248839641 | - |
dc.type.rims | ART | - |
dc.citation.volume | 447 | - |
dc.citation.issue | 4-6 | - |
dc.citation.beginningpage | 197 | - |
dc.citation.endingpage | 201 | - |
dc.citation.publicationname | CHEMICAL PHYSICS LETTERS | - |
dc.identifier.doi | 10.1016/j.cplett.2007.09.024 | - |
dc.contributor.localauthor | Kim, Tae Kyu | - |
dc.contributor.nonIdAuthor | Lee, Gi Woo | - |
dc.contributor.nonIdAuthor | Ahn, Hyeon Geun | - |
dc.contributor.nonIdAuthor | Lee, Sang Kuk | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | SUBSTITUTED BENZYL RADICALS | - |
dc.subject.keywordPlus | P-FLUOROBENZYL | - |
dc.subject.keywordPlus | D-0 TRANSITION | - |
dc.subject.keywordPlus | SPECTROSCOPY | - |
dc.subject.keywordPlus | FLUORESCENCE | - |
dc.subject.keywordPlus | STATES | - |
dc.subject.keywordPlus | XYLYL | - |
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