DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, Eun Hwa | ko |
dc.contributor.author | Reddy, D. Amaranatha | ko |
dc.contributor.author | Hong, Sangyeob | ko |
dc.contributor.author | Park, Hanbit | ko |
dc.contributor.author | Ma, Rory | ko |
dc.contributor.author | Kumar, D. Praveen | ko |
dc.contributor.author | Kim, Tae Kyu | ko |
dc.date.accessioned | 2024-02-29T03:00:24Z | - |
dc.date.available | 2024-02-29T03:00:24Z | - |
dc.date.created | 2024-02-28 | - |
dc.date.created | 2024-02-28 | - |
dc.date.issued | 2017-08 | - |
dc.identifier.citation | JOURNAL OF CATALYSIS, v.352, pp.617 - 626 | - |
dc.identifier.issn | 0021-9517 | - |
dc.identifier.uri | http://hdl.handle.net/10203/318324 | - |
dc.description.abstract | Solar-driven semiconductor-catalyzed photocatalytic water splitting is an important and eco-friendly chemical technique for the production of clean hydrogen fuel. However, a cost-effective, efficient photo catalyst with perfect photon-to-hydrogen molecule conversion remains elusive. Novel, noble-metal-free hybrid nanostructures comprising perovskite (Ba5Nb4O15)-MoS2 ultrathin nanosheets on CdS nanorods, with efficient photo-charge separation and migration capability for efficient solar-driven hydrogen production are designed. The nano-hybrid structures display a high hydrogen production rate of 147 mmol.g(-1).h(-1) in the presence of lactic acid as a sacrificial electron donor under simulated solar irradiation; this value is much higher than those of the CdS/MoS2 (124 mmol.g(-1).h(-1)) and CdS/Ba5Nb4O15 (18 mmol-g(-1).h(-1)) nanostructures and that of the expensive CdS/Pt benchmark catalyst (34.98 mmol.g(-1.)h(-1)). The apparent quantum yield at 425 nm reaches to 28.2% in 5 h. Furthermore, the rate of solar-driven hydrogen evolution in the presence of the ultrathin perovskite Ba5Nb4O15/MoS2 nanohybrid on the CdS nanorods is much faster than that of several noble-metal-free co-catalyst-modified CdS nanostructures reported earlier. UV-Vis absorption, photoluminescence, photocurrent, and impedance analyses of CdS@Ba5Nb4O15/MoS2 reveal that the high photocatalytic hydrogen evolution rate may due to the comparatively higher solar light-harvesting capacity and efficient charge separation and migration, which reduces the recombination rate. We anticipate that the presented design strategy for the development of noble metal-free catalysts combining perovskite and semiconductor nanostructures stimulate the development of diverse non-precious robust solar light-harvesting noble-metal-free materials for water splitting to satisfy the growing global energy demand. (C) 2017 Elsevier Inc. All rights reserved. | - |
dc.language | English | - |
dc.publisher | ACADEMIC PRESS INC ELSEVIER SCIENCE | - |
dc.title | Formation of hybrid nanostructures comprising perovskite (Ba5Nb4O15)-MoS2 ultrathin nanosheets on CdS nanorods: Toward enhanced solar-driven H2 production | - |
dc.type | Article | - |
dc.identifier.wosid | 000408299600063 | - |
dc.identifier.scopusid | 2-s2.0-85024108982 | - |
dc.type.rims | ART | - |
dc.citation.volume | 352 | - |
dc.citation.beginningpage | 617 | - |
dc.citation.endingpage | 626 | - |
dc.citation.publicationname | JOURNAL OF CATALYSIS | - |
dc.identifier.doi | 10.1016/j.jcat.2017.06.033 | - |
dc.contributor.localauthor | Kim, Tae Kyu | - |
dc.contributor.nonIdAuthor | Kim, Eun Hwa | - |
dc.contributor.nonIdAuthor | Reddy, D. Amaranatha | - |
dc.contributor.nonIdAuthor | Hong, Sangyeob | - |
dc.contributor.nonIdAuthor | Park, Hanbit | - |
dc.contributor.nonIdAuthor | Ma, Rory | - |
dc.contributor.nonIdAuthor | Kumar, D. Praveen | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | CdS@Ba5Nb4O15/MoS2 nanohybrid | - |
dc.subject.keywordAuthor | Photocatalytic hydrogen | - |
dc.subject.keywordAuthor | High stability | - |
dc.subject.keywordAuthor | Renewable energy | - |
dc.subject.keywordPlus | EFFICIENT PHOTOCATALYST | - |
dc.subject.keywordPlus | HYDROGEN-PRODUCTION | - |
dc.subject.keywordPlus | MOS2 | - |
dc.subject.keywordPlus | COCATALYST | - |
dc.subject.keywordPlus | EVOLUTION | - |
dc.subject.keywordPlus | PHOTOLUMINESCENCE | - |
dc.subject.keywordPlus | ELECTROCATALYST | - |
dc.subject.keywordPlus | SEMICONDUCTOR | - |
dc.subject.keywordPlus | GENERATION | - |
dc.subject.keywordPlus | BA5NB4O15 | - |
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