DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, Tae Kyu | ko |
dc.contributor.author | Koo, Young-Mi | ko |
dc.contributor.author | Jung, Dong Woon | ko |
dc.contributor.author | Jung, Kwang-Woo | ko |
dc.date.accessioned | 2024-02-29T00:00:44Z | - |
dc.date.available | 2024-02-29T00:00:44Z | - |
dc.date.created | 2024-02-28 | - |
dc.date.created | 2024-02-28 | - |
dc.date.issued | 2008-11 | - |
dc.identifier.citation | BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.29, no.11, pp.2183 - 2188 | - |
dc.identifier.issn | 0253-2964 | - |
dc.identifier.uri | http://hdl.handle.net/10203/318307 | - |
dc.description.abstract | The ion-molecule reactions that proceed inside Ti+(CH2FCH2OH)(n) heterocluster ions were studied using a laser ablation-molecular beam/reflectron time-of-flight mass spectrometric technique. The mass spectra exhibit a major sequence of cluster ions with the formula Ti+(OCH2CH2F)(m)(CH2FCH2OH)(n) (m = 1, 2), which is attributed to sequential insertions of Ti+ into the O-H bond of ethanol molecules within the heteroclusters, followed by H elimination. The TiO+ and TiFOH+ ions produced from the reactions of Ti+ with CH2FCH2OH are interpreted as arising from insertion of Ti+ into the C-O bond, followed by C2H5F and C2H4+ elimination, respectively. The observation of Ti+(H2O)(CH2FCH2OH)(n) ions is attributed to the insertion of Ti+ ions into the C-O bond in the ethanol molecules, leading to a beta-H atom transfer and CH2CHF elimination. This reaction pathway presumably plays an important role as the cluster size increases. A initio calculations on the complexes of Ti+ with CH2FCH2OH molecules show that the minimum energy structure is that in which Ti+ is attached to the O and F atoms of fluorinated ethanol, forming a five-membered ring. The formation mechanisms and reaction energetics of the observed heterocluster ions are discussed. | - |
dc.language | English | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | Chemical Reactivity of Ti+ Ion within Ti+(CH2FCH2OH)n Clusters | - |
dc.type | Article | - |
dc.identifier.wosid | 000262091500020 | - |
dc.identifier.scopusid | 2-s2.0-57349177771 | - |
dc.type.rims | ART | - |
dc.citation.volume | 29 | - |
dc.citation.issue | 11 | - |
dc.citation.beginningpage | 2183 | - |
dc.citation.endingpage | 2188 | - |
dc.citation.publicationname | BULLETIN OF THE KOREAN CHEMICAL SOCIETY | - |
dc.identifier.doi | 10.5012/bkcs.2008.29.11.2183 | - |
dc.identifier.kciid | ART001525635 | - |
dc.contributor.localauthor | Kim, Tae Kyu | - |
dc.contributor.nonIdAuthor | Koo, Young-Mi | - |
dc.contributor.nonIdAuthor | Jung, Dong Woon | - |
dc.contributor.nonIdAuthor | Jung, Kwang-Woo | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | Ion-molecule reaction | - |
dc.subject.keywordAuthor | Titanium | - |
dc.subject.keywordAuthor | 2-Fluoroethanol | - |
dc.subject.keywordAuthor | Heterocluster | - |
dc.subject.keywordPlus | MOLECULE REACTIONS | - |
dc.subject.keywordPlus | METAL-IONS | - |
dc.subject.keywordPlus | COMPLEXES | - |
dc.subject.keywordPlus | CHEMISTRY | - |
dc.subject.keywordPlus | SPECTROSCOPY | - |
dc.subject.keywordPlus | ACTIVATION | - |
dc.subject.keywordPlus | ETHER | - |
dc.subject.keywordPlus | WATER | - |
dc.subject.keywordPlus | BOND | - |
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