DC Field | Value | Language |
---|---|---|
dc.contributor.author | Son, Giyeong | ko |
dc.contributor.author | Ri, Vitalii | ko |
dc.contributor.author | Shin, Donghan | ko |
dc.contributor.author | Jung, Younjoon | ko |
dc.contributor.author | Park, Chan Beum | ko |
dc.contributor.author | Kim, Chunjoong | ko |
dc.date.accessioned | 2023-11-16T02:01:02Z | - |
dc.date.available | 2023-11-16T02:01:02Z | - |
dc.date.created | 2023-10-11 | - |
dc.date.issued | 2023-11 | - |
dc.identifier.citation | ADVANCED SCIENCE, v.10, no.31 | - |
dc.identifier.issn | 2198-3844 | - |
dc.identifier.uri | http://hdl.handle.net/10203/314750 | - |
dc.description.abstract | Herein, the self-reinforced inductive effect derived from coexistence of both p- and n-type redox-active motifs in a single organic molecule is presented. Molecular orbital energy levels of each motif are dramatically tuned, which leads to the higher oxidation and the lower reduction potentials. The self-reinforced inductive effect of the symmetric bipolar organic molecule, N,N'-dimethylquinacridone (DMQA), is corroborated, by both experimental and theoretical methods. Furthermore, its redox mechanism and reaction pathway in the Li+-battery system are scrutinized. DMQA shows excellent capacity retention at the operating voltage of 3.85 and 2.09 V (vs Li+/Li) when used as the cathode and anode, respectively. Successful operation of DMQA electrodes in a symmetric all-organic battery is also demonstrated. The comprehensive insight into the energy storage capability of the symmetric bipolar organic molecule and its self-reinforced inductive effect is provided. Thus, a new class of organic electrode materials for symmetric all-organic batteries as well as conventional rechargeable batteries can be conceived. The authors scrutinize a self-reinforced inductive effect in a bipolar molecule (N,N'-dimethylquinacridone) through experimental and theoretical methods. This effect originates from the coexistence of p- and n-type motifs, and tunes molecular orbital energy levels, leading to a wider potential gap between its oxidation and reduction. Feasible symmetric all-organic battery based on N,N'-dimethylquinacridone is also demonstrated for the first time.image | - |
dc.language | English | - |
dc.publisher | WILEY | - |
dc.title | Self-Reinforced Inductive Effect of Symmetric Bipolar Organic Molecule for High-Performance Rechargeable Batteries | - |
dc.type | Article | - |
dc.identifier.wosid | 001070304500001 | - |
dc.identifier.scopusid | 2-s2.0-85172299413 | - |
dc.type.rims | ART | - |
dc.citation.volume | 10 | - |
dc.citation.issue | 31 | - |
dc.citation.publicationname | ADVANCED SCIENCE | - |
dc.identifier.doi | 10.1002/advs.202301993 | - |
dc.contributor.localauthor | Park, Chan Beum | - |
dc.contributor.nonIdAuthor | Ri, Vitalii | - |
dc.contributor.nonIdAuthor | Shin, Donghan | - |
dc.contributor.nonIdAuthor | Jung, Younjoon | - |
dc.contributor.nonIdAuthor | Kim, Chunjoong | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | all-organic batteries | - |
dc.subject.keywordAuthor | Li-ion batteries | - |
dc.subject.keywordAuthor | organic electrodes | - |
dc.subject.keywordAuthor | self-reinforced inductive effect | - |
dc.subject.keywordAuthor | symmetric bipolar organic molecules | - |
dc.subject.keywordPlus | PIGMENTS | - |
dc.subject.keywordPlus | CHARGE | - |
dc.subject.keywordPlus | SEMICONDUCTORS | - |
dc.subject.keywordPlus | QUINACRIDONE | - |
dc.subject.keywordPlus | STABILITY | - |
dc.subject.keywordPlus | LAYERS | - |
dc.subject.keywordPlus | LIFE | - |
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