DC Field | Value | Language |
---|---|---|
dc.contributor.advisor | Oh, Dong-Young | - |
dc.contributor.advisor | Kim, Sung-Gak | - |
dc.contributor.advisor | 오동영 | - |
dc.contributor.advisor | 김성각 | - |
dc.contributor.author | Kang, Jae-Sung | - |
dc.contributor.author | 강재성 | - |
dc.date.accessioned | 2011-12-13T04:24:32Z | - |
dc.date.available | 2011-12-13T04:24:32Z | - |
dc.date.issued | 1987 | - |
dc.identifier.uri | http://library.kaist.ac.kr/search/detail/view.do?bibCtrlNo=60973&flag=dissertation | - |
dc.identifier.uri | http://hdl.handle.net/10203/31269 | - |
dc.description | 학위논문(박사) - 한국과학기술원 : 화학과, 1987.2, [ viii, 100 p. ] | - |
dc.description.abstract | New mesoionic compounds were synthesized from the reaction of chlorosulfonly isocynate (CSI) or pentachlorophenyl N-chlorosulfonylcarbamate (PCPCSC) with amidine compounds in the presence of ethyldiisopropylamine. CSI or PCPCSC reacted with 2-benzylaminopyridine producing intermediate which was cyclized to afford mesoionic 1-benzylpyrido[1,2-b][1,2,4,6]thiatriazine-2,4,4-trioxide in the presence of tertiary amine base at room temperature. 2-Alkylaminothiazoles afforded mesoionic 1-alkylthiazolo[2,3-c][1,2,4,6]thiatriazine-2,4,4-trioxides with CSI and mesoionic 1-alkylthiazolo[3,2-b]-[1,2,4,6]thiatriazine-2,4,4-trioxideswith PCPCSC in the presence of a tertiary amine base in chloroform at room temperature, respectively. 2-Alkylaminobenzothiazoles frequently gave mixture of mesoionic 4-alkylbenzothiazolo[2,3-c][1,2,4,6]thiatriazine-1,3,3-trioxides and 4-alkylbenzothiazolo-[3,2-b][1,2,4,6]thiatriazine-1,1,3-trioxides with CSI or PCPCSC in the presence of a tertiary amine base. Monocyclic mesoionic compounds were also synthesized. Mesoionic [1,2,4,6]thiatriazine-1,1,3-trioxides were obtained from the reaction of N,N``-disubstituted amidines with CSI or PCPCSC in the presence of ethyldiisopropylamine in chloroform at room temperature. CSI and PCPCSC were good reagents for the synthesis of mesoionic compounds with 1,3-dinitrogen nucleophiles in the presence of ethyldiisopropylamine under mild conditions. | eng |
dc.language | eng | - |
dc.publisher | 한국과학기술원 | - |
dc.title | Syntheses of new mesoionrc compounds | - |
dc.title.alternative | 새로운메소이온 화합물의 합성 | - |
dc.type | Thesis(Ph.D) | - |
dc.identifier.CNRN | 60973/325007 | - |
dc.description.department | 한국과학기술원 : 화학과, | - |
dc.identifier.uid | 000825006 | - |
dc.contributor.localauthor | Oh, Dong-Young | - |
dc.contributor.localauthor | Kim, Sung-Gak | - |
dc.contributor.localauthor | 오동영 | - |
dc.contributor.localauthor | 김성각 | - |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.