DC Field | Value | Language |
---|---|---|
dc.contributor.advisor | Oh, Dong-Young | - |
dc.contributor.advisor | 오동영 | - |
dc.contributor.author | Jo, In-Ho | - |
dc.contributor.author | 조인호 | - |
dc.date.accessioned | 2011-12-13T04:24:26Z | - |
dc.date.available | 2011-12-13T04:24:26Z | - |
dc.date.issued | 1986 | - |
dc.identifier.uri | http://library.kaist.ac.kr/search/detail/view.do?bibCtrlNo=60942&flag=dissertation | - |
dc.identifier.uri | http://hdl.handle.net/10203/31263 | - |
dc.description | 학위논문(박사) - 한국과학기술원 : 화학과, 1986.2, [ vii, 162 p. ] | - |
dc.description.abstract | The reaction of isoquinolinetriones with trialkyl phosphites was investigated and the course of this reaction was monitored by $^{31}P$ NMR spectroscopy. Major products here obtained appeared to be trialkyl phosphate and a condensation dimer, 1,3 (2H,4H)-isoquinolinedion-4-ylidene derivative, formed by the elimination of oxygen of starting material. As a consequence of this investigation it was likely that a mechanism involving carbene intermediate followed by the formation of trialkoxy-phosphorane was reasonable for the formation of trialkyl phosphate and 1,3(2H,4H)-isoquinolinedion-4-ylidene derivative. The reaction of 1,3 (2H,4H)-isoquinolinedion-4-ylidene derivatives with trialkyl phosphites in the presence of water afforded reduction products shown to be 1,3 (2H,4H)-isoquinolinedion-4-yl derivatives by the spectral data and X-ray crystallography. The mass spectra of a series of isoquinolinetriones at 70 eV were obtained and the similarities and differences of their characteristic fragmentations were investigated. | eng |
dc.language | eng | - |
dc.publisher | 한국과학기술원 | - |
dc.title | Reactions of heterocyclic polycarbonyl compounds with trialkyl phosphites | - |
dc.title.alternative | 트리알킬 포스파이트와 헤테로 고리 다중카르보닐 화합물과의 반응 | - |
dc.type | Thesis(Ph.D) | - |
dc.identifier.CNRN | 60942/325007 | - |
dc.description.department | 한국과학기술원 : 화학과, | - |
dc.identifier.uid | 000815266 | - |
dc.contributor.localauthor | Oh, Dong-Young | - |
dc.contributor.localauthor | 오동영 | - |
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