DC Field | Value | Language |
---|---|---|
dc.contributor.author | Lee, Gwangrog | ko |
dc.contributor.author | Nowak, Wiesław | ko |
dc.contributor.author | Jaroniec, Justyna | ko |
dc.contributor.author | Zhang, Qingmin | ko |
dc.contributor.author | Marszalek, Piotr E. | ko |
dc.date.accessioned | 2023-09-12T01:02:43Z | - |
dc.date.available | 2023-09-12T01:02:43Z | - |
dc.date.created | 2023-09-12 | - |
dc.date.issued | 2004-05 | - |
dc.identifier.citation | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.126, no.20, pp.6218 - 6219 | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.uri | http://hdl.handle.net/10203/312460 | - |
dc.description.abstract | Single molecules of β-1 → 6-linked d-glucose polysaccharides, when stretched in an atomic force microscope, display a hookean-like elasticity unusual for polymers. High-level ab initio calculations and microsecond-scale molecular dynamics simulations reveal that this elasticity is governed by force-induced rotations of the exocyclic group on the glucopyranose rings from their short and less energetic gt and gg conformations to the extended and high-energy tg state. These observations indicate that a simple stretching of 1 → 6-linked glucose polysaccharides provide a unique means to control glucopyranose rotamer populations. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Nanomechanical control of glucopyranose rotamers | - |
dc.type | Article | - |
dc.identifier.wosid | 000221526800009 | - |
dc.identifier.scopusid | 2-s2.0-2442705295 | - |
dc.type.rims | ART | - |
dc.citation.volume | 126 | - |
dc.citation.issue | 20 | - |
dc.citation.beginningpage | 6218 | - |
dc.citation.endingpage | 6219 | - |
dc.citation.publicationname | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.identifier.doi | 10.1021/ja0491984 | - |
dc.contributor.localauthor | Lee, Gwangrog | - |
dc.contributor.nonIdAuthor | Nowak, Wiesław | - |
dc.contributor.nonIdAuthor | Jaroniec, Justyna | - |
dc.contributor.nonIdAuthor | Zhang, Qingmin | - |
dc.contributor.nonIdAuthor | Marszalek, Piotr E. | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | MOLECULE FORCE SPECTROSCOPY | - |
dc.subject.keywordPlus | POLYSACCHARIDES | - |
dc.subject.keywordPlus | MICROSCOPY | - |
dc.subject.keywordPlus | CONFORMATIONS | - |
dc.subject.keywordPlus | TRANSITIONS | - |
dc.subject.keywordPlus | RING | - |
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