Modified Fermi's golden rule rate expressions

Cited 6 time in webofscience Cited 0 time in scopus
  • Hit : 71
  • Download : 0
DC FieldValueLanguage
dc.contributor.authorJang, Seogjoo J.ko
dc.contributor.authorRhee, Young Minko
dc.date.accessioned2023-08-14T06:01:02Z-
dc.date.available2023-08-14T06:01:02Z-
dc.date.created2023-08-14-
dc.date.created2023-08-14-
dc.date.issued2023-07-
dc.identifier.citationJOURNAL OF CHEMICAL PHYSICS, v.159, no.1-
dc.identifier.issn0021-9606-
dc.identifier.urihttp://hdl.handle.net/10203/311486-
dc.description.abstractFermi's golden rule (FGR) serves as the basis for many expressions of spectroscopic observables and quantum transition rates. The utility of FGR has been demonstrated through decades of experimental confirmation. However, there still remain important cases where the evaluation of a FGR rate is ambiguous or ill-defined. Examples are cases where the rate has divergent terms due to the sparsity in the density of final states or time dependent fluctuations of system Hamiltonians. Strictly speaking, assumptions of FGR are no longer valid for such cases. However, it is still possible to define modified FGR rate expressions that are useful as effective rates. The resulting modified FGR rate expressions resolve a long standing ambiguity often encountered in using FGR and offer more reliable ways to model general rate processes. Simple model calculations illustrate the utility and implications of new rate expressions.-
dc.languageEnglish-
dc.publisherAIP Publishing-
dc.titleModified Fermi's golden rule rate expressions-
dc.typeArticle-
dc.identifier.wosid001023455600012-
dc.identifier.scopusid2-s2.0-85163954013-
dc.type.rimsART-
dc.citation.volume159-
dc.citation.issue1-
dc.citation.publicationnameJOURNAL OF CHEMICAL PHYSICS-
dc.identifier.doi10.1063/5.0152804-
dc.contributor.localauthorRhee, Young Min-
dc.contributor.nonIdAuthorJang, Seogjoo J.-
dc.description.isOpenAccessN-
dc.type.journalArticleArticle-
dc.subject.keywordPlusELECTRON-TRANSFER-
dc.subject.keywordPlusCHARGE-TRANSFER-
dc.subject.keywordPlusENERGY-
dc.subject.keywordPlusSOLVENTS-
dc.subject.keywordPlusMODEL-
Appears in Collection
CH-Journal Papers(저널논문)
Files in This Item
There are no files associated with this item.
This item is cited by other documents in WoS
⊙ Detail Information in WoSⓡ Click to see webofscience_button
⊙ Cited 6 items in WoS Click to see citing articles in records_button

qr_code

  • mendeley

    citeulike


rss_1.0 rss_2.0 atom_1.0