DC Field | Value | Language |
---|---|---|
dc.contributor.author | Shin, Bong-Rim | ko |
dc.contributor.author | Yu, In Cheol | ko |
dc.contributor.author | Puc, Uros | ko |
dc.contributor.author | Kim, Won Tae | ko |
dc.contributor.author | Yoon, Woojin | ko |
dc.contributor.author | Kim, Chaeyoon | ko |
dc.contributor.author | Yun, Hoseop | ko |
dc.contributor.author | Kim, Dongwook | ko |
dc.contributor.author | Jazbinsek, Mojca | ko |
dc.contributor.author | Rotermund, Fabian | ko |
dc.contributor.author | Kwon, O-Pil | ko |
dc.date.accessioned | 2023-07-21T01:01:03Z | - |
dc.date.available | 2023-07-21T01:01:03Z | - |
dc.date.created | 2022-11-07 | - |
dc.date.created | 2022-11-07 | - |
dc.date.issued | 2023-07 | - |
dc.identifier.citation | ADVANCED OPTICAL MATERIALS, v.11, no.13 | - |
dc.identifier.issn | 2195-1071 | - |
dc.identifier.uri | http://hdl.handle.net/10203/310742 | - |
dc.description.abstract | Development of new organic crystals possessing large second-order optical nonlinearity is very challenging because of strong tendency of centrosymmetric dipole-dipole molecular assembly in crystals. This tendency makes it difficult to develop various analogous crystals that allow fine tuning of optical and physical properties to enhance the device performance. A design approach of an isomorphic crystal library consisting of 11 highly efficient nonlinear optical salt crystals is reported. Analyzing the so-called isomorphic tolerance space in previously reported mother crystals (PMnXQ chromophores, where PM denotes piperidin-4-ylmethanol electron donor, n corresponds to the substituted position of halogen (X) group on the quinolinium (Q) electron acceptor), various substituents are introduced into the PMnXQ crystals at different positions, considering their space-filling characteristics and interionic interaction ability. All 11 PMnXQ crystals exhibit an isomorphic (or pseudo-isomorphic) crystal structure, in which the cationic chromophores form a perfectly parallel assembly for maximizing the second-order nonlinear optical susceptibility. The optical, physical, and crystal characteristics of newly designed, synthesized, and grown isomorphic PMnXQ crystals show both similarities and differences. Excellent THz wave-generation performance is demonstrated in both kHz- and MHz-repetition optical pump systems with new PMnXQ crystals. Therefore, the design approach using isomorphic tolerance space is very attractive for developing diverse isomorphic analogous organic crystals. | - |
dc.language | English | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | Design and Validation of Isomorphic Crystal Library for Nonlinear Optics and THz Wave Generation | - |
dc.type | Article | - |
dc.identifier.wosid | 000872149200001 | - |
dc.identifier.scopusid | 2-s2.0-85140431621 | - |
dc.type.rims | ART | - |
dc.citation.volume | 11 | - |
dc.citation.issue | 13 | - |
dc.citation.publicationname | ADVANCED OPTICAL MATERIALS | - |
dc.identifier.doi | 10.1002/adom.202201420 | - |
dc.contributor.localauthor | Rotermund, Fabian | - |
dc.contributor.nonIdAuthor | Shin, Bong-Rim | - |
dc.contributor.nonIdAuthor | Puc, Uros | - |
dc.contributor.nonIdAuthor | Yoon, Woojin | - |
dc.contributor.nonIdAuthor | Yun, Hoseop | - |
dc.contributor.nonIdAuthor | Kim, Dongwook | - |
dc.contributor.nonIdAuthor | Jazbinsek, Mojca | - |
dc.contributor.nonIdAuthor | Kwon, O-Pil | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | nonlinear optics | - |
dc.subject.keywordAuthor | organic crystals | - |
dc.subject.keywordAuthor | terahertz waves | - |
dc.subject.keywordPlus | SINGLE-CRYSTALS | - |
dc.subject.keywordPlus | TOLERANCE FACTOR | - |
dc.subject.keywordPlus | ORGANIC SALTS | - |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.