Site-selective functionalization of pyridine derivatives and alkenes via visible-light-mediated photocatalysis가시광선 매개의 광촉매 반응을 통한 피리딘 유도체 및 알켄의 위치선택적 기능화에 대한 연구

Cited 0 time in webofscience Cited 0 time in scopus
  • Hit : 131
  • Download : 0
DC FieldValueLanguage
dc.contributor.authorLee, Kangjae-
dc.date.accessioned2023-06-23T19:35:28Z-
dc.date.available2023-06-23T19:35:28Z-
dc.date.issued2022-
dc.identifier.urihttp://library.kaist.ac.kr/search/detail/view.do?bibCtrlNo=1000314&flag=dissertationen_US
dc.identifier.urihttp://hdl.handle.net/10203/309410-
dc.description학위논문(박사) - 한국과학기술원 : 화학과, 2022.2,[ii, 120 p. :]-
dc.description.abstractPyridine is a widespread moiety which is frequently found in medical compounds and fine chemicals, and its functionalization reactions have been intensely studied, but challenging points such as selectivity and over-reactivity due to the existence of several reaction sites still remain. In addition, alkene, which is used as a simple building block for complex structures, is commonly used for atom- and step-economical difunctionalization based on the advantages of high reactivity and accessibility, while site-selectivity is one of the major issues during the reaction. Therefore, in this thesis, I introduced a series of reactions overcoming such limitation with pyridium salts through radical-based mechanism under visible-light-mediated photocatalytic system to maintain the intrinsic reactivity, induce the predominance of one regioisomeric product over another, and enable the late-stage functionalization of bioactive molecules under mild conditions.-
dc.languageeng-
dc.publisher한국과학기술원-
dc.subjectPyridine derivative▼aAlkene▼aSite-selectivity▼aVisible light▼aPhotocatalysis▼aLate-stage functionalization-
dc.subject피리딘 유도체▼a알켄▼a위치선택성▼a가시광선▼a광촉매 반응▼a후기 기능화-
dc.titleSite-selective functionalization of pyridine derivatives and alkenes via visible-light-mediated photocatalysis-
dc.title.alternative가시광선 매개의 광촉매 반응을 통한 피리딘 유도체 및 알켄의 위치선택적 기능화에 대한 연구-
dc.typeThesis(Ph.D)-
dc.identifier.CNRN325007-
dc.description.department한국과학기술원 :화학과,-
dc.contributor.alternativeauthor이강재-
Appears in Collection
CH-Theses_Ph.D.(박사논문)
Files in This Item
There are no files associated with this item.

qr_code

  • mendeley

    citeulike


rss_1.0 rss_2.0 atom_1.0