DC Field | Value | Language |
---|---|---|
dc.contributor.author | Park, Yoonsu | ko |
dc.contributor.author | Zhong, Hongyu | ko |
dc.contributor.author | Pabst, Tyler P. | ko |
dc.contributor.author | Kim, Junho | ko |
dc.contributor.author | Chirik, Paul J. | ko |
dc.date.accessioned | 2023-04-24T06:00:36Z | - |
dc.date.available | 2023-04-24T06:00:36Z | - |
dc.date.created | 2023-04-24 | - |
dc.date.created | 2023-04-24 | - |
dc.date.issued | 2023-03 | - |
dc.identifier.citation | ORGANOMETALLICS, v.42, no.6, pp.465 - 472 | - |
dc.identifier.issn | 0276-7333 | - |
dc.identifier.uri | http://hdl.handle.net/10203/306364 | - |
dc.description.abstract | The synthesis and characterization of pentamethylcy-clopentadienyl iron complexes bearing the redox noninnocent alpha- diimine (N,N '-dimesitylbutane-2,3-diimine, MesDI) and alpha-iminopyr-idine (N-mesityl(pyridin-2-yl)ethanimine MesPI) ligands were explored. One-pot reduction and complexation of the cyclopentadienyl ring was accomplished by treatment of (kappa 2-N,N ')FeCl2 (N,N '= MesDI or MesPI) precursors with [C5Me5]Li. The resulting iron compounds were characterized by paramagnetic 1H NMR spectroscopy, magnetic susceptibility measurements, zero-field 57Fe Mo''ssbauer spectroscopy, low-temperature electron paramagnetic resonance (EPR) spectroscopy, and cyclic voltammetry. The combined spectroscopic, structural, and density functional theory (DFT) computational data supported low-spin iron(III) compounds (SFe = 1/2) with pi-acidic, formally doubly reduced chelating ligands. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Pentamethylcyclopentadienyl Metalloradical Iron Complexes Containing Redox Noninnocent ?-Diimine-Type Ligands: Synthesis, Molecular, and Electronic Structures | - |
dc.type | Article | - |
dc.identifier.wosid | 000956824900001 | - |
dc.identifier.scopusid | 2-s2.0-85150411543 | - |
dc.type.rims | ART | - |
dc.citation.volume | 42 | - |
dc.citation.issue | 6 | - |
dc.citation.beginningpage | 465 | - |
dc.citation.endingpage | 472 | - |
dc.citation.publicationname | ORGANOMETALLICS | - |
dc.identifier.doi | 10.1021/acs.organomet.3c00027 | - |
dc.contributor.localauthor | Park, Yoonsu | - |
dc.contributor.nonIdAuthor | Zhong, Hongyu | - |
dc.contributor.nonIdAuthor | Pabst, Tyler P. | - |
dc.contributor.nonIdAuthor | Kim, Junho | - |
dc.contributor.nonIdAuthor | Chirik, Paul J. | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | CYCLOPENTADIENYLIRON DICARBONYL | - |
dc.subject.keywordPlus | HEME-PROTEINS | - |
dc.subject.keywordPlus | HYDROGENATION | - |
dc.subject.keywordPlus | THERMODYNAMICS | - |
dc.subject.keywordPlus | GENERATION | - |
dc.subject.keywordPlus | MECHANISM | - |
dc.subject.keywordPlus | CATALYSIS | - |
dc.subject.keywordPlus | OXIDATION | - |
dc.subject.keywordPlus | KINETICS | - |
dc.subject.keywordPlus | HYDRIDES | - |
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