DC Field | Value | Language |
---|---|---|
dc.contributor.author | Cha, Han Lim | ko |
dc.contributor.author | Yun, Jong-Il | ko |
dc.date.accessioned | 2023-03-21T01:02:12Z | - |
dc.date.available | 2023-03-21T01:02:12Z | - |
dc.date.created | 2023-03-21 | - |
dc.date.created | 2023-03-21 | - |
dc.date.issued | 2023-02 | - |
dc.identifier.citation | JOURNAL OF THE ELECTROCHEMICAL SOCIETY, v.170, no.2 | - |
dc.identifier.issn | 0013-4651 | - |
dc.identifier.uri | http://hdl.handle.net/10203/305686 | - |
dc.description.abstract | This study demonstrates the pulsed-potential electrodeposition of reduced Zr species (ZrCl and Zr) in a molten LiCl-KCl salt. We report, for the first time, a new reduction reaction of Zr species (-1.90 V vs Ag/AgCl 10 wt%) in molten LiCl-KCl salt, characterized by cyclic-voltammetry experiments using W and Zr electrodes. The pulsed-potential electrodeposition experiments were performed using an inert W-foil electrode in a molten ZrCl4-LiCl-KCl salt. Three cathodic-pulse potentials (-1.30, -1.60, and -1.90 V) were applied, and the chemical and structural characteristics of respective deposits were compared. The deposits were characterized by scanning electron microscopy with energy-dispersive x-ray spectroscopy, x-ray diffraction analysis, and Raman spectroscopy. Additionally, we accomplished the pulsed-potential electrodeposition (>10(3) A m(-2)) of alpha-Zr metal with a practical ZrCl4 concentration (2.6 wt%). The results confirm that pulsed-potential electrodeposition can be employed for the selective deposition of the alpha-Zr metal by minimizing the co-production of ZrCl in molten LiCl-KCl salt while achieving excellent adhesion to the inert W electrode. | - |
dc.language | English | - |
dc.publisher | ELECTROCHEMICAL SOC INC | - |
dc.title | Pulsed-Potential Electrodeposition of Zirconium in a Molten LiCl-KCl Salt: Improvements in the Selectivity and Adhesion Strength | - |
dc.type | Article | - |
dc.identifier.wosid | 000940765100001 | - |
dc.identifier.scopusid | 2-s2.0-85149625419 | - |
dc.type.rims | ART | - |
dc.citation.volume | 170 | - |
dc.citation.issue | 2 | - |
dc.citation.publicationname | JOURNAL OF THE ELECTROCHEMICAL SOCIETY | - |
dc.identifier.doi | 10.1149/1945-7111/acbc9a | - |
dc.contributor.localauthor | Yun, Jong-Il | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | ELECTROCHEMICAL-BEHAVIOR | - |
dc.subject.keywordPlus | CLADDING HULLS | - |
dc.subject.keywordPlus | METAL | - |
dc.subject.keywordPlus | ZR | - |
dc.subject.keywordPlus | CHLORIDE | - |
dc.subject.keywordPlus | DEPOSITION | - |
dc.subject.keywordPlus | TITANIUM | - |
dc.subject.keywordPlus | DECONTAMINATION | - |
dc.subject.keywordPlus | MONOCHLORIDE | - |
dc.subject.keywordPlus | LIF-KF-ZRF4 | - |
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