DC Field | Value | Language |
---|---|---|
dc.contributor.author | Ahn, Nam Young | ko |
dc.contributor.author | Lee, Jooyeon | ko |
dc.contributor.author | Yeo, Wonjune | ko |
dc.contributor.author | Park, Hyojin | ko |
dc.contributor.author | Nam, Jiyun | ko |
dc.contributor.author | Kim, Min | ko |
dc.contributor.author | Seo, Myungeun | ko |
dc.date.accessioned | 2022-12-19T03:02:56Z | - |
dc.date.available | 2022-12-19T03:02:56Z | - |
dc.date.created | 2022-07-26 | - |
dc.date.created | 2022-07-26 | - |
dc.date.issued | 2022-06 | - |
dc.identifier.citation | INORGANIC CHEMISTRY, v.61, no.27, pp.10365 - 10372 | - |
dc.identifier.issn | 0020-1669 | - |
dc.identifier.uri | http://hdl.handle.net/10203/303181 | - |
dc.description.abstract | We report a synthetic methodology for decorating a surface of metal-organic frameworks (MOFs) with polymers through postsynthetic modification. Well-defined polymers with reversibly deactivated radical species at their chain end were reacted with vinyl-functionalized MOFs in the presence of a radical initiator. The radical addition forms a C-C bond between the polymer end with the functional group at the MOF ligand. We used sterically bulky star polymers containing electron-deficient maleimide chain ends, which facilitated modification of the external surface, yielding polymer-grafted MOF composite particles. A patchy MOF particle can also be obtained by simultaneously grafting two polymers and jammed at the immiscible liquid-liquid interface. We further show that the selective removal of a sacrificial polymer would partially expose the surface of MOFs to external environment, which hinders the uptake of macromolecular guests above the critical hydrodynamic size. Overall, four polymer@MOF composites have successfully been achieved through the present postsynthetic patchworks on MOFs with star polymers and selective etching process. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Patchwork Metal-Organic Frameworks by Radical-Mediated Heterografting of Star for Surface Modification | - |
dc.type | Article | - |
dc.identifier.wosid | 000821804900001 | - |
dc.identifier.scopusid | 2-s2.0-85134426465 | - |
dc.type.rims | ART | - |
dc.citation.volume | 61 | - |
dc.citation.issue | 27 | - |
dc.citation.beginningpage | 10365 | - |
dc.citation.endingpage | 10372 | - |
dc.citation.publicationname | INORGANIC CHEMISTRY | - |
dc.identifier.doi | 10.1021/acs.inorgchem.2c00906 | - |
dc.contributor.localauthor | Seo, Myungeun | - |
dc.contributor.nonIdAuthor | Lee, Jooyeon | - |
dc.contributor.nonIdAuthor | Park, Hyojin | - |
dc.contributor.nonIdAuthor | Kim, Min | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | RAFT COPOLYMERIZATION | - |
dc.subject.keywordPlus | POLYMERIZATION | - |
dc.subject.keywordPlus | POLYMERS | - |
dc.subject.keywordPlus | COMPOSITES | - |
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