DC Field | Value | Language |
---|---|---|
dc.contributor.author | Jeong, Jiwoo | ko |
dc.contributor.author | Jung, Hoimin | ko |
dc.contributor.author | Kim, Dongwook | ko |
dc.contributor.author | Chang, Sukbok | ko |
dc.date.accessioned | 2022-12-19T02:01:34Z | - |
dc.date.available | 2022-12-19T02:01:34Z | - |
dc.date.created | 2022-07-11 | - |
dc.date.created | 2022-07-11 | - |
dc.date.issued | 2022-06 | - |
dc.identifier.citation | ACS CATALYSIS, v.12, no.13, pp.8127 - 8138 | - |
dc.identifier.issn | 2155-5435 | - |
dc.identifier.uri | http://hdl.handle.net/10203/303155 | - |
dc.description.abstract | We report herein a series of tailored (CpRh)-Rh-X(LX)Cl catalyst systems for the outer-sphere C-H amidations discovered by high-throughput experimentation. Using a diverse repertoire of Cp-tunable group 9 [(CpXCl2)-Cl-M](2) precatalysts in combination with bidentate LX-type co-ligands, we have established a premixing protocol for the fast and convenient in situ generation of an array of half- sandwich metal complexes. Benefitting from the designed multidimensional approach to simultaneously screen the metal center, Cp-X, LX-type co-ligands, and nitrene precursors, optimal CpXRh(III)(LX) catalysts were quickly identified for intra- and intermolecular C-H amidations and also for an enantioselective transformation using N-tosyloxycarbamates as the nitrenoid precursor. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Multidimensional Screening Accelerates the Discovery of Rhodium Catalyst Systems for Selective Intra- and Intermolecular C-H Amidations | - |
dc.type | Article | - |
dc.identifier.wosid | 000818695200001 | - |
dc.identifier.scopusid | 2-s2.0-85135064698 | - |
dc.type.rims | ART | - |
dc.citation.volume | 12 | - |
dc.citation.issue | 13 | - |
dc.citation.beginningpage | 8127 | - |
dc.citation.endingpage | 8138 | - |
dc.citation.publicationname | ACS CATALYSIS | - |
dc.identifier.doi | 10.1021/acscatal.2c02612 | - |
dc.contributor.localauthor | Chang, Sukbok | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | C-H amidation | - |
dc.subject.keywordAuthor | rhodium | - |
dc.subject.keywordAuthor | catalysis | - |
dc.subject.keywordAuthor | high-throughput experimentation | - |
dc.subject.keywordAuthor | parallel screening | - |
dc.subject.keywordAuthor | intramolecular | - |
dc.subject.keywordAuthor | intermolecular | - |
dc.subject.keywordPlus | HIGH-THROUGHPUT EXPERIMENTATION | - |
dc.subject.keywordPlus | N BOND FORMATION | - |
dc.subject.keywordPlus | OXIDATIVE ANNULATION | - |
dc.subject.keywordPlus | BIARYL COMPOUNDS | - |
dc.subject.keywordPlus | AMIDO TRANSFER | - |
dc.subject.keywordPlus | GAMMA-LACTAMS | - |
dc.subject.keywordPlus | AMINATION | - |
dc.subject.keywordPlus | LIGANDS | - |
dc.subject.keywordPlus | ACTIVATION | - |
dc.subject.keywordPlus | COMPLEXES | - |
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