DC Field | Value | Language |
---|---|---|
dc.contributor.advisor | Lee, Won-Kook | - |
dc.contributor.advisor | 이원국 | - |
dc.contributor.author | Jeong, Gweon | - |
dc.contributor.author | 정권 | - |
dc.date.accessioned | 2011-12-13T02:01:27Z | - |
dc.date.available | 2011-12-13T02:01:27Z | - |
dc.date.issued | 1979 | - |
dc.identifier.uri | http://library.kaist.ac.kr/search/detail/view.do?bibCtrlNo=62433&flag=dissertation | - |
dc.identifier.uri | http://hdl.handle.net/10203/30077 | - |
dc.description | 학위논문 (석사) - 한국과학기술원 : 화학공학과, 1979.2, [ [iv], 80 p. ] | - |
dc.description.abstract | Main pollutants in automobile exhaust gases can be controlled by the following reaction in a catalytic reactor. $$NO\,+\,CO\;-\;\frac{1}{2}N_2\,+\,CO_2$$ The reaction was studied in view of the effects of the operating conditions and thermal treating of the catalysts on reaction rates by using copper chromite catalysts in a integral reactor. Two types of copper chromite, normal and spinel type, were used in this experiment. The normal type catalyst contained CuO and $CuCr_2O_4$, and spinel type catalyst was almost pure $CuCr_2O_4$. After thermal treating at 800$^\circ$C for 24 hours, the activity of the spinel type slightly decreased, but that of normal type decreased markedly to 50\% of the thermally untreated one. At low CO concentration $(3<CO/NO<8)$, the kinetics of this reaction exhibited an effective reaction order of unity with respect to NO. However at relatively high CO concentration $(CO/NO>8)$ CO caused reaction inhibition. By analyzing the experiental data, the following rate equation based on the adsorption control model was obtained. $$r_m = \frac{4.04 \exp(-2600/RT) C_{NO}}{1+1.29 \times 10^5 \exp(-11270/RT)C_{CO}}$$ The system performances were taken at temperature range of 150 - 270$^\circ$C, 1000 to 6000 ppm of No and 1 to 5\% CO, and contact times in the order of tenths of a second. | eng |
dc.language | eng | - |
dc.publisher | 한국과학기술원 | - |
dc.title | Nitric oxide reduction with carbon monoxide over copper chromite catalyst | - |
dc.title.alternative | Copper chromite 촉매상에서 일산화탄소에 의한 일산화질소의 환원반응 | - |
dc.type | Thesis(Master) | - |
dc.identifier.CNRN | 62433/325007 | - |
dc.description.department | 한국과학기술원 : 화학공학과, | - |
dc.identifier.uid | 000771139 | - |
dc.contributor.localauthor | Lee, Won-Kook | - |
dc.contributor.localauthor | 이원국 | - |
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