DC Field | Value | Language |
---|---|---|
dc.contributor.author | Park, J.W. | ko |
dc.contributor.author | Kim, Sung Chul | ko |
dc.date.accessioned | 2008-02-11T02:40:32Z | - |
dc.date.available | 2008-02-11T02:40:32Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 1995-08 | - |
dc.identifier.citation | POLYMERS FOR ADVANCED TECHNOLOGIES, v.7, no.4, pp.209 - 220 | - |
dc.identifier.issn | 1042-7147 | - |
dc.identifier.uri | http://hdl.handle.net/10203/2995 | - |
dc.description.abstract | The phase separation behavior and the morphology of polyetherimide (PEI)-modified diglycidyl ether of bisphenol A (DGEBA) epoxy resin were studied using scanning electron microscopy and light scattering. Reaction kinetics, cloud point and onset of gelation were determined by differential scanning calorimeter, optical microscope and physica rheometer, respectively. The mixture of partially cured epoxy and PEI showed bimodal upper critical solution temperature (UCST) behavior. For PEI content smaller than 10 wt%, the blends exhibited a sea-island morphology formed via nucleation and a growth mechanism. Above 25 wt% PEI content, th phase separation proceeded via a spinodal decomposition mechanism and a nodular structure was formed. With PEI content between 15 and 20 wt%, dual phase morphology was observed. This morphology was formed via primary spinodal decomposition and secondary phase separation within the dispersed phases and the matrix phases formed by the primary phase separation. This morphology was presumed to be formed in the reaction-induced phase separation mechanism with the mixture showing bimodal UCST behavior. The curing temperature had an effect on the final morphology, and the modulus of PEI-modified epoxy was influenced by the phase separation. | - |
dc.language | English | - |
dc.language.iso | en_US | en |
dc.publisher | Wiley-Blackwell | - |
dc.subject | RUBBER-MODIFIED EPOXIES | - |
dc.subject | TOUGHENING MECHANISMS | - |
dc.subject | PARTICLE-SIZE | - |
dc.subject | MATRIX RESIN | - |
dc.subject | MORPHOLOGY | - |
dc.subject | BEHAVIOR | - |
dc.subject | POLYETHERSULFONE | - |
dc.subject | THERMOPLASTICS | - |
dc.subject | SULFONE) | - |
dc.subject | BLENDS | - |
dc.title | Phase separation during synthesis of polyetherimide/epoxy semi-IPNs | - |
dc.type | Article | - |
dc.identifier.wosid | A1996UT98400003 | - |
dc.identifier.scopusid | 2-s2.0-0030121572 | - |
dc.type.rims | ART | - |
dc.citation.volume | 7 | - |
dc.citation.issue | 4 | - |
dc.citation.beginningpage | 209 | - |
dc.citation.endingpage | 220 | - |
dc.citation.publicationname | POLYMERS FOR ADVANCED TECHNOLOGIES | - |
dc.embargo.liftdate | 9999-12-31 | - |
dc.embargo.terms | 9999-12-31 | - |
dc.contributor.localauthor | Kim, Sung Chul | - |
dc.contributor.nonIdAuthor | Park, J.W. | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | phase separation | - |
dc.subject.keywordAuthor | morphology | - |
dc.subject.keywordAuthor | polyetherimide | - |
dc.subject.keywordAuthor | epoxy | - |
dc.subject.keywordAuthor | semi-IPN | - |
dc.subject.keywordPlus | RUBBER-MODIFIED EPOXIES | - |
dc.subject.keywordPlus | TOUGHENING MECHANISMS | - |
dc.subject.keywordPlus | PARTICLE-SIZE | - |
dc.subject.keywordPlus | MATRIX RESIN | - |
dc.subject.keywordPlus | MORPHOLOGY | - |
dc.subject.keywordPlus | BEHAVIOR | - |
dc.subject.keywordPlus | POLYETHERSULFONE | - |
dc.subject.keywordPlus | THERMOPLASTICS | - |
dc.subject.keywordPlus | SULFONE) | - |
dc.subject.keywordPlus | BLENDS | - |
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