DC Field | Value | Language |
---|---|---|
dc.contributor.author | Thangasamy, Pitchai | ko |
dc.contributor.author | Oh, Saewoong | ko |
dc.contributor.author | Randriamahazaka, Hyacinthe | ko |
dc.contributor.author | Nam, Sanghee | ko |
dc.contributor.author | Oh, Il-Kwon | ko |
dc.date.accessioned | 2022-07-13T08:00:13Z | - |
dc.date.available | 2022-07-13T08:00:13Z | - |
dc.date.created | 2022-07-04 | - |
dc.date.created | 2022-07-04 | - |
dc.date.created | 2022-07-04 | - |
dc.date.created | 2022-07-04 | - |
dc.date.created | 2022-07-04 | - |
dc.date.issued | 2022-11 | - |
dc.identifier.citation | APPLIED CATALYSIS B-ENVIRONMENTAL, v.316 | - |
dc.identifier.issn | 0926-3373 | - |
dc.identifier.uri | http://hdl.handle.net/10203/297365 | - |
dc.description.abstract | Here, we report a collectively exhaustive CoPi-NPC (cobalt phosphate moieties incorporated into the N, P- doped carbon) nanosheets for oxygen reduction reaction (ORR) and rechargeable zinc-air battery (ZAB) applications. The unprecedented CoPi-NPC nanosheets were synthesized from the cobalt-diethyl dithiocarbamate coordination complex by using room-temperature crystallization and carbonization processes. The fabricated nanosheets catalyze the critical ORR via a four-electron transfer through an associative reaction pathway in which the Osingle bondO bond cleavage can be recognized as the rate-determining step, offering high positive onset (∼0.925 V vs. RHE) and the half-wave potentials (E1/2 = ∼0.796 V vs. RHE). The assembled ZAB based on porous CoPi-NPC-900 air cathode delivered the maximum power density of ∼186 mW cm−2, and large specific capacity of ∼729 mAh g−1. Hence, this study opens up a new avenue to exploit various efficient non-precious electrocatalysts through different transition metal-diethyl dithiocarbamate coordination complexes. | - |
dc.language | English | - |
dc.publisher | ELSEVIER | - |
dc.title | Mechanistic insight into collectively exhaustive CoPi-NPC nanosheets for oxygen reduction reaction and Zn-air battery | - |
dc.type | Article | - |
dc.identifier.wosid | 000827134800001 | - |
dc.identifier.scopusid | 2-s2.0-85135410478 | - |
dc.type.rims | ART | - |
dc.citation.volume | 316 | - |
dc.citation.publicationname | APPLIED CATALYSIS B-ENVIRONMENTAL | - |
dc.identifier.doi | 10.1016/j.apcatb.2022.121656 | - |
dc.contributor.localauthor | Oh, Il-Kwon | - |
dc.contributor.nonIdAuthor | Thangasamy, Pitchai | - |
dc.contributor.nonIdAuthor | Randriamahazaka, Hyacinthe | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | CoPi-NPC-900 nanosheets | - |
dc.subject.keywordAuthor | Violet-crystals | - |
dc.subject.keywordAuthor | Cobalt-diethyl dithiocarbamate complex | - |
dc.subject.keywordAuthor | Oxygen reduction reaction | - |
dc.subject.keywordAuthor | Zinc-air battery | - |
dc.subject.keywordPlus | RAY-ABSORPTION SPECTRATRANSITION-METALCOBALTCATALYSTSGRAPHENENITROGENELECTROCATALYSTSPERFORMANCEPOLYMERLAYERS | - |
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