DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, Hong Ki | ko |
dc.contributor.author | Jung, Jong-Yeong | ko |
dc.contributor.author | Kang, Gyumin | ko |
dc.contributor.author | Baik, Mu-Hyun | ko |
dc.contributor.author | Choi, Eun-Young | ko |
dc.date.accessioned | 2022-06-06T03:00:58Z | - |
dc.date.available | 2022-06-06T03:00:58Z | - |
dc.date.created | 2022-06-06 | - |
dc.date.created | 2022-06-06 | - |
dc.date.created | 2022-06-06 | - |
dc.date.created | 2022-06-06 | - |
dc.date.issued | 2022-05 | - |
dc.identifier.citation | NPJ COMPUTATIONAL MATERIALS, v.8, no.1 | - |
dc.identifier.issn | 2057-3960 | - |
dc.identifier.uri | http://hdl.handle.net/10203/296808 | - |
dc.description.abstract | Enhancing the stability and durability of metal-organic frameworks (MOFs) is vital for practical applications because many promising MOF materials suffer from phase transitions and/or structural decompositions with humidity being a particularly damaging condition. In mechanical engineering, the frame of buildings and furniture can be stabilized significantly by installing a truss beam. Employing the same principle, we functionalized the organic component of MOF-5 to contain a carbazole moiety that can act as a molecular truss beam by reaching across the corner and forming a stable pi-pi interaction with a phenyl group on the edge position of the MOF-skeleton. This structural support enhanced the stability of the MOF substantially, allowing the designed MOF to maintain compositional integrity under steam conditions at 90 degrees C for similar to 5 days. The unmodified MOF-5 shows clear signs of structural collapse after similar to 1 h. | - |
dc.language | English | - |
dc.publisher | NATURE PORTFOLIO | - |
dc.title | Installing a molecular truss beam stabilizes MOF structures | - |
dc.type | Article | - |
dc.identifier.wosid | 000799812600001 | - |
dc.identifier.scopusid | 2-s2.0-85130734684 | - |
dc.type.rims | ART | - |
dc.citation.volume | 8 | - |
dc.citation.issue | 1 | - |
dc.citation.publicationname | NPJ COMPUTATIONAL MATERIALS | - |
dc.identifier.doi | 10.1038/s41524-022-00799-3 | - |
dc.contributor.localauthor | Baik, Mu-Hyun | - |
dc.contributor.nonIdAuthor | Kim, Hong Ki | - |
dc.contributor.nonIdAuthor | Choi, Eun-Young | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | METAL-ORGANIC FRAMEWORKS | - |
dc.subject.keywordPlus | EFFECTIVE CORE POTENTIALS | - |
dc.subject.keywordPlus | POROUS COORDINATION POLYMERS | - |
dc.subject.keywordPlus | CARBON-DIOXIDE | - |
dc.subject.keywordPlus | HYDROGEN STORAGE | - |
dc.subject.keywordPlus | WATER STABILITY | - |
dc.subject.keywordPlus | BASIS-SETS | - |
dc.subject.keywordPlus | ADSORPTION | - |
dc.subject.keywordPlus | RESISTANT | - |
dc.subject.keywordPlus | SELECTIVITY | - |
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