DC Field | Value | Language |
---|---|---|
dc.contributor.advisor | Lee, Hee-Seung | - |
dc.contributor.advisor | 이희승 | - |
dc.contributor.author | Lee, Jihee | - |
dc.date.accessioned | 2022-04-27T19:32:55Z | - |
dc.date.available | 2022-04-27T19:32:55Z | - |
dc.date.issued | 2021 | - |
dc.identifier.uri | http://library.kaist.ac.kr/search/detail/view.do?bibCtrlNo=963498&flag=dissertation | en_US |
dc.identifier.uri | http://hdl.handle.net/10203/296287 | - |
dc.description | 학위논문(석사) - 한국과학기술원 : 화학과, 2021.8,[iii, 50 p. :] | - |
dc.description.abstract | Research using thioether functional group found in the natural amino acid, methionine, is a promising research topic in peptidomimetics and bioinorganics. Thioether has the potential to allow for a variety of chemical modi-fications, as well as coordination using a characteristic of a soft Lewis base. In this thesis I address, a series of α/β-peptide, featuring ATTC ((3S,4R)-4-aminotetrahydrothiophene-3-carboxylic acid), were synthesized, and structural specificity were identified in solid and solution states. Further-more, by coordinating ATTC as a ligand with CuX, novel structures were obtained, and explored optical proper-ties and thermal stability. This research, using sulfur-containing β-amino acid, not only indicates the possibility that it can be used to extend the library of foldamers and to control elaborative self-assembled structures, but also suggests ligand designs for coordination complex controlled structure and properties. | - |
dc.language | eng | - |
dc.publisher | 한국과학기술원 | - |
dc.subject | Thioether▼aα/β-peptide▼aHeteroatom foldamer▼aMetal—sulfur bond▼aCopper(Ⅰ) halide | - |
dc.subject | 싸이오에터▼aα/β-펩타이드▼a헤테로원자 폴대머▼a금속-황 결합▼a구리(Ⅰ) 할로젠화물 | - |
dc.title | Studies on artificial peptides and coordination complexes using tetrahydrothiophene-based chiral β-amino acid | - |
dc.title.alternative | 테트라하이드로싸이오펜 기반 카이랄 베타-아미노산을 이용한 인공 펩타이드와 배위화합물에 관한 연구 | - |
dc.type | Thesis(Master) | - |
dc.identifier.CNRN | 325007 | - |
dc.description.department | 한국과학기술원 :화학과, | - |
dc.contributor.alternativeauthor | 이지희 | - |
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