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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

Diastereoselective C-H Bond Amination for Disubstituted Pyrrolidines

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dc.contributor.authorIovan, Diana A.ko
dc.contributor.authorWilding, Matthew J. T.ko
dc.contributor.authorBaek, Yunjungko
dc.contributor.authorHennessy, Elisabeth T.ko
dc.contributor.authorBetley, Theodore A.ko
dc.date.accessioned2022-04-16T06:42:19Z-
dc.date.available2022-04-16T06:42:19Z-
dc.date.created2022-04-04-
dc.date.issued2017-12-
dc.identifier.citationANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.56, no.49, pp.15599 - 15602-
dc.identifier.issn1433-7851-
dc.identifier.urihttp://hdl.handle.net/10203/295165-
dc.description.abstractWe report herein the improved diastereoselective synthesis of 2,5-disubstituted pyrrolidines from aliphatic azides. Experimental and theoretical studies of the C-H amination reaction mediated by the iron dipyrrinato complex (L-Ad)FeCl(OEt2) provided a model for diastereoinduction and allowed for systematic variation of the catalyst to enhance selectivity. Among the iron alkoxide and aryloxide catalysts evaluated, the iron phenoxide complex exhibited superior performance towards the generation of syn 2,5-disubstituted pyrrolidines with high diastereoselectivity.-
dc.languageEnglish-
dc.publisherWILEY-V C H VERLAG GMBH-
dc.titleDiastereoselective C-H Bond Amination for Disubstituted Pyrrolidines-
dc.typeArticle-
dc.identifier.wosid000416244200017-
dc.identifier.scopusid2-s2.0-85033484855-
dc.type.rimsART-
dc.citation.volume56-
dc.citation.issue49-
dc.citation.beginningpage15599-
dc.citation.endingpage15602-
dc.citation.publicationnameANGEWANDTE CHEMIE-INTERNATIONAL EDITION-
dc.identifier.doi10.1002/anie.201708519-
dc.contributor.localauthorBaek, Yunjung-
dc.contributor.nonIdAuthorIovan, Diana A.-
dc.contributor.nonIdAuthorWilding, Matthew J. T.-
dc.contributor.nonIdAuthorHennessy, Elisabeth T.-
dc.contributor.nonIdAuthorBetley, Theodore A.-
dc.description.isOpenAccessN-
dc.type.journalArticleArticle-
dc.subject.keywordAuthorC-H activation-
dc.subject.keywordAuthordiastereoselectivity-
dc.subject.keywordAuthoriron-
dc.subject.keywordAuthorphenoxide-
dc.subject.keywordAuthorpyrrolidine-
dc.subject.keywordPlusASYMMETRIC-SYNTHESIS-
dc.subject.keywordPlus2,5-DISUBSTITUTED PYRROLIDINES-
dc.subject.keywordPlusCIS-2,5-DISUBSTITUTED PYRROLIDINES-
dc.subject.keywordPlusTRANS-2,5-DISUBSTITUTED PYRROLIDINES-
dc.subject.keywordPlusSTEREOSELECTIVE-SYNTHESIS-
dc.subject.keywordPlusCYCLOADDITION-
dc.subject.keywordPlusCYCLIZATION-
dc.subject.keywordPlusOXAZOLIDINES-
dc.subject.keywordPlusPIPERIDINE-
dc.subject.keywordPlusCOMPLEXES-
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