Ir(iii)-Catalysed electrooxidative intramolecular dehydrogenative C-H/N-H coupling for the synthesis of N-H indoles

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Herein, an iridium(iii)-catalysed electrooxidative intramolecular dehydrogenative C-H/N-H coupling of unprotected 2-alkenyl anilines is described. The developed method allows the synthesis of a variety of 3-substituted N-H indole scaffolds under undivided electrolytic conditions. Mechanistic studies suggest that the reaction proceeds through the electro-oxidation induced reductive elimination pathway.
Publisher
ROYAL SOC CHEMISTRY
Issue Date
2021-11
Language
English
Article Type
Article
Citation

CHEMICAL COMMUNICATIONS, v.57, no.92, pp.12309 - 12312

ISSN
1359-7345
DOI
10.1039/d1cc05882g
URI
http://hdl.handle.net/10203/289464
Appears in Collection
CH-Journal Papers(저널논문)
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