DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, Junggil | ko |
dc.contributor.author | Kim, Sang Kyu | ko |
dc.date.accessioned | 2021-11-23T06:44:08Z | - |
dc.date.available | 2021-11-23T06:44:08Z | - |
dc.date.created | 2021-11-22 | - |
dc.date.created | 2021-11-22 | - |
dc.date.created | 2021-11-22 | - |
dc.date.issued | 2021-10 | - |
dc.identifier.citation | JOURNAL OF CHEMICAL PHYSICS, v.155, no.16 | - |
dc.identifier.issn | 0021-9606 | - |
dc.identifier.uri | http://hdl.handle.net/10203/289385 | - |
dc.description.abstract | Photofragmentation dynamics of cis and trans isomers of 1,2-dibromoethylene (1,2-DBE) have been investigated by multiphoton excitation using a picosecond (ps) laser pulse. It has been found that the Br-2(+) product ion preferentially originates from the cis isomer rather than from trans. The Boltzmann-type isotropic low kinetic energy components of the Br+ and Br-2(+) product state distributions seem to be most likely from the unimolecular reactions of the vibrationally hot cationic ground state generated by the three-photon absorption at the photon energy below & SIM;38 000 cm(-1). The highly anisotropic kinetic energy components of Br+ and Br-2(+) start to appear at the photon energy above & SIM;38 000 cm(-1), where the D-n (n & GE; 1) - D-0 transition is facilitated within the same ps laser pulse as the parent molecule is efficiently ionized by the two-photon absorption. The transition dipole moment of the D-4 - D-0 transition of the strongest oscillator strength has been theoretically predicted to be parallel to the C-Br bond or C=C bond axis for the trans or cis isomer, respectively. The fast anisotropic with the (beta & SIM; +2) component in the Br+ product distribution is thus likely from the trans isomer, whereas that of Br-2(+) (beta & SIM; -0.5) should be the consequence of the photodissociation of the cis isomer. The isomer-specific reactivity found here in the picosecond multiphoton excitation of 1,2-DBE provides a nice platform for the better understanding of the structure-reactivity relationship under the harsh condition of the strong or ultrashort optical field.</p> | - |
dc.language | English | - |
dc.publisher | AIP Publishing | - |
dc.title | Multiphoton-excited dynamics of the trans or cis structural isomer of 1,2-dibromoethylene | - |
dc.type | Article | - |
dc.identifier.wosid | 000715617200004 | - |
dc.identifier.scopusid | 2-s2.0-85118429402 | - |
dc.type.rims | ART | - |
dc.citation.volume | 155 | - |
dc.citation.issue | 16 | - |
dc.citation.publicationname | JOURNAL OF CHEMICAL PHYSICS | - |
dc.identifier.doi | 10.1063/5.0067643 | - |
dc.embargo.liftdate | 9999-12-31 | - |
dc.embargo.terms | 9999-12-31 | - |
dc.contributor.localauthor | Kim, Sang Kyu | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | 248 NM | - |
dc.subject.keywordPlus | PHOTODISSOCIATION | - |
dc.subject.keywordPlus | CHEMISTRY | - |
dc.subject.keywordPlus | SPECTRA | - |
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