DC Field | Value | Language |
---|---|---|
dc.contributor.author | Lee, Young Hun | ko |
dc.contributor.author | Kwon, Yongsung | ko |
dc.contributor.author | Kim, Chaehoon | ko |
dc.contributor.author | Hwang, Young-Eun | ko |
dc.contributor.author | Choi, Minkee | ko |
dc.contributor.author | Park, Youin | ko |
dc.contributor.author | Jamal, Aqil | ko |
dc.contributor.author | Koh, Dong-Yeun | ko |
dc.date.accessioned | 2021-09-08T06:10:21Z | - |
dc.date.available | 2021-09-08T06:10:21Z | - |
dc.date.created | 2021-09-08 | - |
dc.date.created | 2021-09-08 | - |
dc.date.created | 2021-09-08 | - |
dc.date.created | 2021-09-08 | - |
dc.date.issued | 2021-08 | - |
dc.identifier.citation | JACS AU, v.1, no.8, pp.1198 - 1207 | - |
dc.identifier.issn | 2691-3704 | - |
dc.identifier.uri | http://hdl.handle.net/10203/287651 | - |
dc.description.abstract | Metal-organic frameworks (MOFs) are a class of microporous materials that have been highlighted with fast and selective sorption of gas molecules; however, they are at least partially unstable in the scale-up process. Here, we report a rational shaping of MOFs in a scalable architecture of fiber sorbent. The long-standing stability challenge of MOFs was resolved by using stable metal oxide precursors that are subject to controlled surface oxide dissolution-growth chemistry during the Mg-based MOF synthesis. Highly uniform MOF crystals are synthesized along with the open-porous fiber sorbents networks, showing unprecedented cyclic CO2 capacities in both flue gas and direct air capture (DAC) conditions. The same chemistry enables an in situ flow synthesis of Mg-MOF fiber sorbents, providing a scalable pathway for MOF synthesis in an inert condition with minimal handling steps. This modular approach can serve both as a reaction stage for enhanced MOF fiber sorbent synthesis and as a "process-ready" separation device. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Controlled Synthesis of Metal-Organic Frameworks in Scalable Open-Porous Contactor for Maximizing Carbon Capture Efficiency | - |
dc.type | Article | - |
dc.identifier.scopusid | 2-s2.0-85122522653 | - |
dc.type.rims | ART | - |
dc.citation.volume | 1 | - |
dc.citation.issue | 8 | - |
dc.citation.beginningpage | 1198 | - |
dc.citation.endingpage | 1207 | - |
dc.citation.publicationname | JACS AU | - |
dc.identifier.doi | 10.1021/jacsau.1c00068 | - |
dc.contributor.localauthor | Choi, Minkee | - |
dc.contributor.localauthor | Koh, Dong-Yeun | - |
dc.contributor.nonIdAuthor | Park, Youin | - |
dc.contributor.nonIdAuthor | Jamal, Aqil | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | metal-organic frameworks | - |
dc.subject.keywordAuthor | fiber sorbents | - |
dc.subject.keywordAuthor | controlled-dissolution synthesis | - |
dc.subject.keywordAuthor | postspinning conversion | - |
dc.subject.keywordAuthor | amine functionalization | - |
dc.subject.keywordAuthor | carbon capture and storage | - |
dc.subject.keywordPlus | HOLLOW-FIBER SORBENTS | - |
dc.subject.keywordPlus | CO2 CAPTURE | - |
dc.subject.keywordPlus | DIOXIDE | - |
dc.subject.keywordPlus | ADSORPTION | - |
dc.subject.keywordPlus | GAS | - |
dc.subject.keywordPlus | POLY(ETHYLENEIMINE) | - |
dc.subject.keywordPlus | ADSORBENTS | - |
dc.subject.keywordPlus | MECHANISM | - |
dc.subject.keywordPlus | DESIGN | - |
dc.subject.keywordPlus | AIR | - |
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