DC Field | Value | Language |
---|---|---|
dc.contributor.author | Sarango-Ramirez, Marvin K. | ko |
dc.contributor.author | Park, Junkil | ko |
dc.contributor.author | Kim, Jihan | ko |
dc.contributor.author | Yoshida, Yukihiro | ko |
dc.contributor.author | Lim, Dae-Woon | ko |
dc.contributor.author | Kitagawa, Hiroshi | ko |
dc.date.accessioned | 2021-09-04T08:30:24Z | - |
dc.date.available | 2021-09-04T08:30:24Z | - |
dc.date.created | 2021-07-19 | - |
dc.date.created | 2021-07-19 | - |
dc.date.created | 2021-07-19 | - |
dc.date.created | 2021-07-19 | - |
dc.date.issued | 2021-09 | - |
dc.identifier.citation | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.60, no.37, pp.20173 - 20177 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.uri | http://hdl.handle.net/10203/287620 | - |
dc.description.abstract | Void space and functionality of the pore surface are important structural factors for proton-conductive metal-organic frameworks (MOFs) impregnated with conducting media. However, no clear study has compared their priority factors, which need to be considered when designing proton-conductive MOFs. Herein, we demonstrate the effects of void space and pore-surface modification on proton conduction in MOFs through the surface-modified isoreticular MOF-74(Ni) series [Ni-2(dobdc or dobpdc), dobdc=2,5-dihydroxy-1,4-benzenedicarboxylate and dobpdc=4,4 '-dihydroxy-(1,1 '-biphenyl)-3,3 '-dicarboxylate]. The MOF with lower porosity with the same surface functionality showed higher proton conductivity than that with higher porosity despite including a smaller amount of conducting medium. Density functional theory calculations suggest that strong hydrogen bonding between molecules of the conducting medium at high porosity is inefficient in inducing high proton conductivity. | - |
dc.language | English | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | Void Space versus Surface Functionalization for Proton Conduction in Metal-Organic Frameworks | - |
dc.type | Article | - |
dc.identifier.wosid | 000668458400001 | - |
dc.identifier.scopusid | 2-s2.0-85113690235 | - |
dc.type.rims | ART | - |
dc.citation.volume | 60 | - |
dc.citation.issue | 37 | - |
dc.citation.beginningpage | 20173 | - |
dc.citation.endingpage | 20177 | - |
dc.citation.publicationname | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.identifier.doi | 10.1002/anie.202106181 | - |
dc.embargo.liftdate | 9999-12-31 | - |
dc.embargo.terms | 9999-12-31 | - |
dc.contributor.localauthor | Kim, Jihan | - |
dc.contributor.nonIdAuthor | Sarango-Ramirez, Marvin K. | - |
dc.contributor.nonIdAuthor | Yoshida, Yukihiro | - |
dc.contributor.nonIdAuthor | Lim, Dae-Woon | - |
dc.contributor.nonIdAuthor | Kitagawa, Hiroshi | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | functionality | - |
dc.subject.keywordAuthor | metal-organic frameworks | - |
dc.subject.keywordAuthor | postsynthetic modification | - |
dc.subject.keywordAuthor | proton conductivity | - |
dc.subject.keywordAuthor | void space | - |
dc.subject.keywordPlus | WATER | - |
dc.subject.keywordPlus | TRANSPORT | - |
dc.subject.keywordPlus | UREA | - |
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