DC Field | Value | Language |
---|---|---|
dc.contributor.advisor | Ihee, Hyotcherl | - |
dc.contributor.advisor | 이효철 | - |
dc.contributor.author | Park, Sungjun | - |
dc.date.accessioned | 2021-05-11T19:42:52Z | - |
dc.date.available | 2021-05-11T19:42:52Z | - |
dc.date.issued | 2020 | - |
dc.identifier.uri | http://library.kaist.ac.kr/search/detail/view.do?bibCtrlNo=907044&flag=dissertation | en_US |
dc.identifier.uri | http://hdl.handle.net/10203/283533 | - |
dc.description | 학위논문(박사) - 한국과학기술원 : 화학과, 2020.2,[v, 71 p. :] | - |
dc.description.abstract | The work presented in this thesis addresses structural dynamics studies of two different systems using time-resolved X-ray solution scattering. Diiodomethane, $CH_2I_2$, in a polar solvent undergoes a unique photoinduced reaction whereby $I_2^−$ and $I_3^−$ are produced from its photodissociation, unlike for other iodine-containing haloalkanes. While previous studies proposed that homolysis, heterolysis, or solvolysis of iso-$CH_2I$-I, which is a major intermediate of the photodissociation, can account for the formation of $I_2^−$ and $I_3^−$, there has been no consensus on its mechanism and no clue for the reason why those negative ionic species are not observed in the photodissociation of other iodine-containing chemicals in the same polar solvent, for example, $CHI_3, C_2H_4I_2, C2F4I2, I_3^−, and I_2$. Here, using time-resolved X-ray solution scattering, we revisit the photodissociation mechanism of $CH_2I_2$ in methanol and determine the structures of all transient species and photoproducts involved in its photodissociation, and reveal that $I_2^−$ and $I_3^−$ are formed via heterolysis of iso-$CH_2I$−I in the photodissociation of $CH_2I_2$ in methanol. In addition, we demonstrate that the high polarity of iso-$CH_2I$−I is responsible for the unique photochemistry of $CH_2I_2$. We report the successful synthesis of Au nanoparticles from liquid solutions by synchrotron X-ray irradiation. By use of X-ray scattering methods, the structural relaxations in condensed matter, and in particular in nanoscale systems are directly accessible. Gold particles were fabricated by the X-ray irradiation of gold (III) terpyridine complex aqueous solution. The structure and size distribution of the prepared particles were evaluated by transmission electron microscopy and time-resolved X-ray solution scattering. Following the laser pulse, shape and angular shift of the Bragg reflection from crystalline gold nanoparticles are resolved stroboscopically using 100 ps X-ray pulses from a synchrotron. We observed the lattice expansion and relaxation of AuNPs heated by intense femtosecond laser pulse are measured by time-resolved X-ray solution scattering. | - |
dc.language | eng | - |
dc.publisher | 한국과학기술원 | - |
dc.subject | time-resolved X-ray solution scattering▼adiiodomethane▼ananostructures▼aphotoreaction▼amechanism | - |
dc.subject | 용액상 시간분해 엑스선 산란법▼a요오드화메틸렌▼a나노 구조체▼a광반응▼a메커니즘 | - |
dc.title | Structural dynamics study of small molecules and nanostructures using time-resolved X-ray solution scattering | - |
dc.title.alternative | 용액상 시간분해 X-선 산란법을 이용한 작은 분자 및 나노 구조체의 동역학 연구 | - |
dc.type | Thesis(Ph.D) | - |
dc.identifier.CNRN | 325007 | - |
dc.description.department | 한국과학기술원 :화학과, | - |
dc.contributor.alternativeauthor | 박성준 | - |
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