DC Field | Value | Language |
---|---|---|
dc.contributor.author | Yang, H. | ko |
dc.contributor.author | Boudrioua, O. | ko |
dc.contributor.author | Mayne, A. J. | ko |
dc.contributor.author | Comtet, G. | ko |
dc.contributor.author | Dujardin, G. | ko |
dc.contributor.author | Kuk, Y. | ko |
dc.contributor.author | Sonnet, Ph | ko |
dc.contributor.author | Stauffer, L. | ko |
dc.contributor.author | Nagarajan, S. | ko |
dc.contributor.author | Gourdon, A. | ko |
dc.date.accessioned | 2021-01-28T06:14:46Z | - |
dc.date.available | 2021-01-28T06:14:46Z | - |
dc.date.created | 2021-01-26 | - |
dc.date.created | 2021-01-26 | - |
dc.date.issued | 2012 | - |
dc.identifier.citation | PHYSICAL CHEMISTRY CHEMICAL PHYSICS, v.14, no.5, pp.1700 - 1705 | - |
dc.identifier.issn | 1463-9076 | - |
dc.identifier.uri | http://hdl.handle.net/10203/280243 | - |
dc.description.abstract | Controlling the intrinsic optical and electronic properties of a single molecule adsorbed on a surface requires electronic decoupling of some molecular orbitals from the surface states. Scanning tunneling microscopy experiments and density functional theory calculations are used to study a perylene molecule derivative (DHH-PTCDI), adsorbed on the clean 3 x 3 reconstructed wide band gap silicon carbide surface (SiC(0001)-3 x 3). We find that the LUMO of the adsorbed molecule is invisible in I(V) spectra due to the absence of any surface or bulk states and that the HOMO has a very low saturation current in I(z) spectra. These results present a paradox that the molecular orbitals are electronically isolated from the surface of the wide band gap semiconductor even though strong chemical bonds are formed. | - |
dc.language | English | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.title | The paradox of an insulating contact between a chemisorbed molecule and a wide band gap semiconductor surface | - |
dc.type | Article | - |
dc.identifier.wosid | 000299113000021 | - |
dc.identifier.scopusid | 2-s2.0-84862908029 | - |
dc.type.rims | ART | - |
dc.citation.volume | 14 | - |
dc.citation.issue | 5 | - |
dc.citation.beginningpage | 1700 | - |
dc.citation.endingpage | 1705 | - |
dc.citation.publicationname | PHYSICAL CHEMISTRY CHEMICAL PHYSICS | - |
dc.identifier.doi | 10.1039/c2cp23104b | - |
dc.contributor.localauthor | Yang, H. | - |
dc.contributor.nonIdAuthor | Boudrioua, O. | - |
dc.contributor.nonIdAuthor | Mayne, A. J. | - |
dc.contributor.nonIdAuthor | Comtet, G. | - |
dc.contributor.nonIdAuthor | Dujardin, G. | - |
dc.contributor.nonIdAuthor | Kuk, Y. | - |
dc.contributor.nonIdAuthor | Sonnet, Ph | - |
dc.contributor.nonIdAuthor | Stauffer, L. | - |
dc.contributor.nonIdAuthor | Nagarajan, S. | - |
dc.contributor.nonIdAuthor | Gourdon, A. | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | PTCDA | - |
dc.subject.keywordPlus | ELECTRONICS | - |
dc.subject.keywordPlus | TRANSPORT | - |
dc.subject.keywordPlus | GROWTH | - |
dc.subject.keywordPlus | FILMS | - |
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