DC Field | Value | Language |
---|---|---|
dc.contributor.author | Velioglu, Sadiye | ko |
dc.contributor.author | Karahan, Huseyin Enis | ko |
dc.contributor.author | Goh, Kunli | ko |
dc.contributor.author | Bae, Tae-Hyun | ko |
dc.contributor.author | Chen, Yuan | ko |
dc.contributor.author | Chew, Jia Wei | ko |
dc.date.accessioned | 2020-09-18T04:02:04Z | - |
dc.date.available | 2020-09-18T04:02:04Z | - |
dc.date.created | 2020-06-08 | - |
dc.date.issued | 2020-06 | - |
dc.identifier.citation | SMALL, v.16, no.25, pp.1907575 | - |
dc.identifier.issn | 1613-6810 | - |
dc.identifier.uri | http://hdl.handle.net/10203/276118 | - |
dc.description.abstract | Carbon nanotubes (CNTs) with hydrophobic and atomically smooth inner channels are promising for building ultrahigh-flux nanofluidic platforms for energy harvesting, health monitoring, and water purification. Conventional wisdom is that nanoconfinement effects determine water transport in CNTs. Here, using full-atomistic molecular dynamics simulations, it is shown that water transport behavior in CNTs strongly correlates with the electronic properties of single-walled CNTs (metallic (met) vs semiconducting (s/c)), which is as dominant as the effect of nanoconfinement. Three pairs of CNTs (i.e., (8,8)(met), 10.85 angstrom vs (9,7)(s/c), 10.88 angstrom; (9,8)(s/c), 11.53 angstrom vs (10,7)(met), 11.59 angstrom; and (9,9)(met), 12.20 angstrom vs (10,8)(s/c), 12.23 angstrom) are used to investigate the roles of diameter and metallicity. Specifically, the (9,8)(s/c) can restrict the hydrogen-bonding-mediated structuring of water and give the highest reduction in carbon-water interaction energy, providing an extraordinarily high water flux, around 250 times that of the commercial reverse osmosis membranes and approximately fourfold higher than the flux of the state-of-the-art boron nitrate nanotubes. Further, the high performance of (9,8)(s/c) is also reproducible when embedded in lipid bilayers as synthetic high-water flux porins. Given the increasing availability of high-purity CNTs, these findings provide valuable guides for realizing novel CNT-enhanced nanofluidic systems. | - |
dc.language | English | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | Metallicity-Dependent Ultrafast Water Transport in Carbon Nanotubes | - |
dc.type | Article | - |
dc.identifier.wosid | 000534396100001 | - |
dc.identifier.scopusid | 2-s2.0-85085014827 | - |
dc.type.rims | ART | - |
dc.citation.volume | 16 | - |
dc.citation.issue | 25 | - |
dc.citation.beginningpage | 1907575 | - |
dc.citation.publicationname | SMALL | - |
dc.identifier.doi | 10.1002/smll.201907575 | - |
dc.contributor.localauthor | Bae, Tae-Hyun | - |
dc.contributor.nonIdAuthor | Velioglu, Sadiye | - |
dc.contributor.nonIdAuthor | Karahan, Huseyin Enis | - |
dc.contributor.nonIdAuthor | Goh, Kunli | - |
dc.contributor.nonIdAuthor | Chen, Yuan | - |
dc.contributor.nonIdAuthor | Chew, Jia Wei | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | chirality | - |
dc.subject.keywordAuthor | metallicity | - |
dc.subject.keywordAuthor | molecular dynamics | - |
dc.subject.keywordAuthor | nanofluidics | - |
dc.subject.keywordAuthor | water transport | - |
dc.subject.keywordPlus | MEMBRANES | - |
dc.subject.keywordPlus | PERMEABILITY | - |
dc.subject.keywordPlus | PURIFICATION | - |
dc.subject.keywordPlus | PERFORMANCE | - |
dc.subject.keywordPlus | TECHNOLOGY | - |
dc.subject.keywordPlus | FUTURE | - |
dc.subject.keywordPlus | FLOW | - |
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