DC Field | Value | Language |
---|---|---|
dc.contributor.author | Jang, Youngho | ko |
dc.contributor.author | Han, Sunkyu | ko |
dc.date.accessioned | 2020-06-08T01:20:06Z | - |
dc.date.available | 2020-06-08T01:20:06Z | - |
dc.date.created | 2020-06-06 | - |
dc.date.created | 2020-06-06 | - |
dc.date.created | 2020-06-06 | - |
dc.date.created | 2020-06-06 | - |
dc.date.issued | 2020-06 | - |
dc.identifier.citation | JOURNAL OF ORGANIC CHEMISTRY, v.85, no.11, pp.7576 - 7582 | - |
dc.identifier.issn | 0022-3263 | - |
dc.identifier.uri | http://hdl.handle.net/10203/274582 | - |
dc.description.abstract | We describe the first total synthesis of cinnamodial-based dimer (−)-capsicodendrin. First, we developed a 12-step synthetic route to access (−)-cinnamodial from 1-vinyl-2,6,6-trimethylcyclohexene. We then showed that (−)-cinnamodial can selectively dimerize to (−)-capsicodendrin under kinetically controlled basic conditions. Our observations regarding a facile conversion of (−)-capsicodendrin back to (−)-cinnamodial hint at the possibility that (−)-capsicodendrin is a chemical reservoir of insecticidal (−)-cinnamodial and Cinnamosma genus plants release it upon environmental stresses. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Total Synthesis of Cinnamodial-Based Dimer (-)-Capsicodendrin | - |
dc.type | Article | - |
dc.identifier.wosid | 000538764000073 | - |
dc.identifier.scopusid | 2-s2.0-85087378551 | - |
dc.type.rims | ART | - |
dc.citation.volume | 85 | - |
dc.citation.issue | 11 | - |
dc.citation.beginningpage | 7576 | - |
dc.citation.endingpage | 7582 | - |
dc.citation.publicationname | JOURNAL OF ORGANIC CHEMISTRY | - |
dc.identifier.doi | 10.1021/acs.joc.0c00740 | - |
dc.contributor.localauthor | Han, Sunkyu | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | DRIMANE SESQUITERPENOIDS | - |
dc.subject.keywordPlus | A-C | - |
dc.subject.keywordPlus | FRAGRANS | - |
dc.subject.keywordPlus | TRANSFORMATION | - |
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