DC Field | Value | Language |
---|---|---|
dc.contributor.author | Choi, Jonghoon | ko |
dc.contributor.author | Lee, Yunho | ko |
dc.date.accessioned | 2020-05-29T07:20:05Z | - |
dc.date.available | 2020-05-29T07:20:05Z | - |
dc.date.created | 2020-01-30 | - |
dc.date.created | 2020-01-30 | - |
dc.date.created | 2020-01-30 | - |
dc.date.created | 2020-01-30 | - |
dc.date.issued | 2020-05 | - |
dc.identifier.citation | INORGANIC CHEMISTRY FRONTIERS, v.7, no.9, pp.1845 - 1850 | - |
dc.identifier.issn | 2052-1553 | - |
dc.identifier.uri | http://hdl.handle.net/10203/274348 | - |
dc.description.abstract | A diphosphinoamido cobalt scaffold was employed for studying catalytic CO2 hydrogenation. Particularly, the dissociative ligand loss of a cobalt catalyst induced by a formate product has been investigated. A structurally rigidified ligand leads to the reduction of the basicity of an amido moiety of a cobalt complex, thus revealing higher catalyst performance relative to the original ligand. With a robust N-Co moiety, the hydrolytic stability of the catalyst toward an accumulated conjugate acid [DBUH][OCHO] has been dramatically improved. | - |
dc.language | English | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.title | Catalytic hydrogenation of CO2 at a structurally rigidified cobalt center | - |
dc.type | Article | - |
dc.identifier.wosid | 000532231700014 | - |
dc.identifier.scopusid | 2-s2.0-85085970446 | - |
dc.type.rims | ART | - |
dc.citation.volume | 7 | - |
dc.citation.issue | 9 | - |
dc.citation.beginningpage | 1845 | - |
dc.citation.endingpage | 1850 | - |
dc.citation.publicationname | INORGANIC CHEMISTRY FRONTIERS | - |
dc.identifier.doi | 10.1039/c9qi01431d | - |
dc.contributor.localauthor | Lee, Yunho | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | CARBON-DIOXIDE | - |
dc.subject.keywordPlus | REVERSIBLE HYDROGENATION | - |
dc.subject.keywordPlus | REACTIVITY | - |
dc.subject.keywordPlus | NICKEL | - |
dc.subject.keywordPlus | ACID | - |
dc.subject.keywordPlus | COMPLEXES | - |
dc.subject.keywordPlus | IRIDIUM | - |
dc.subject.keywordPlus | FORMATE | - |
dc.subject.keywordPlus | IRON | - |
dc.subject.keywordPlus | H-2 | - |
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