DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, Seji | ko |
dc.contributor.author | Lee, Yunho | ko |
dc.date.accessioned | 2020-04-01T08:20:11Z | - |
dc.date.available | 2020-04-01T08:20:11Z | - |
dc.date.created | 2020-01-13 | - |
dc.date.created | 2020-01-13 | - |
dc.date.created | 2020-01-13 | - |
dc.date.issued | 2020-03 | - |
dc.identifier.citation | INORGANIC CHEMISTRY FRONTIERS, v.7, no.5, pp.1172 - 1181 | - |
dc.identifier.issn | 2052-1553 | - |
dc.identifier.uri | http://hdl.handle.net/10203/273769 | - |
dc.description.abstract | A novel cobalt system featuring a Co-P moiety has been synthesized to study its metal-ligand cooperativity. A reversible conversion of a phosphide group to a P-P bond found in a dimeric cobalt(i) complex involves electron transfer between Co and P, in which a single electron transfer is successfully coupled with a redox change in each cobalt ion. Upon coordination of a pi-acidic ligand such as acetonitrile and isocyanide at the cobalt site, the transformation of a dimeric to a monomeric cobalt complex occurs, which involves the migration of a phenolate group. During the conversion, a P-P bond was cleaved and converted to phosphide and phosphinite. Current Co-P metal-ligand cooperativity presented in this work has been explored structurally, spectroscopically and theoretically. | - |
dc.language | English | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.title | Metal-Ligand Cooperativity of a Co-P Moiety | - |
dc.type | Article | - |
dc.identifier.wosid | 000519117700007 | - |
dc.identifier.scopusid | 2-s2.0-85081381247 | - |
dc.type.rims | ART | - |
dc.citation.volume | 7 | - |
dc.citation.issue | 5 | - |
dc.citation.beginningpage | 1172 | - |
dc.citation.endingpage | 1181 | - |
dc.citation.publicationname | INORGANIC CHEMISTRY FRONTIERS | - |
dc.identifier.doi | 10.1039/c9qi01517e | - |
dc.contributor.localauthor | Lee, Yunho | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | PHOSPHIDO PINCER COMPLEXES | - |
dc.subject.keywordPlus | THIOLATE | - |
dc.subject.keywordPlus | COORDINATION | - |
dc.subject.keywordPlus | COPPER(I) | - |
dc.subject.keywordPlus | BIS(MU-THIOLATO)DICOPPER(II) | - |
dc.subject.keywordPlus | INTERCONVERSION | - |
dc.subject.keywordPlus | SUSCEPTIBILITY | - |
dc.subject.keywordPlus | CHEMISTRY | - |
dc.subject.keywordPlus | COMPOUND | - |
dc.subject.keywordPlus | BEHAVIOR | - |
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