DC Field | Value | Language |
---|---|---|
dc.contributor.author | Han, Moon Jong | ko |
dc.contributor.author | McBride, Michael | ko |
dc.contributor.author | Risteen, Bailey | ko |
dc.contributor.author | Zhang, Guoyan | ko |
dc.contributor.author | Khau, Brian V. | ko |
dc.contributor.author | Reichmanis, Elsa | ko |
dc.contributor.author | Yoon, Dong Ki | ko |
dc.date.accessioned | 2020-03-19T02:21:06Z | - |
dc.date.available | 2020-03-19T02:21:06Z | - |
dc.date.created | 2020-02-18 | - |
dc.date.created | 2020-02-18 | - |
dc.date.created | 2020-02-18 | - |
dc.date.issued | 2020-01 | - |
dc.identifier.citation | CHEMISTRY OF MATERIALS, v.32, no.2, pp.688 - 696 | - |
dc.identifier.issn | 0897-4756 | - |
dc.identifier.uri | http://hdl.handle.net/10203/272587 | - |
dc.description.abstract | We fabricate organic field effect transistor (OFET) devices based on highly aligned aggregates of the conjugated polymer, poly[3-(potassium-7-hexanoate)-thiophene-2,5-diyl] (P3PHT), using self-organized DNA as a matrix. P3PHT is a water-soluble conjugated semiconducting polymer, which can be well-mixed with DNA to afford a P3PHT/DNA blend that can be effectively aligned by a simple shearing method. The charge carrier mobility of P3PHT is correlated with its orientation, which is related to inter- and/or intramolecular charge transport: mobility of the P3PHT/DNA blend along the pi-conjugation direction is 3 orders of magnitude higher compared to the case of neat P3PHT owing to the versatility of DNA as a template and charge injection layer. Additionally, the specific chemical interactions and physical electrostatic binding affinities between DNA and Cu2+ enables p-doping, affording hole mobilities as high as 0.22 cm(2)V(-1) s(-1), which represents the highest reported values for water-soluble polythiophene materials. The interdisciplinary convergence between DNA nanotechnology and aqueous processed organic devices can provide important guidelines for the design of sustainable and efficient organic optoelectronic devices. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Highly Oriented and Ordered Water-Soluble Semiconducting Polymers in a DNA Matrix | - |
dc.type | Article | - |
dc.identifier.wosid | 000510530500006 | - |
dc.identifier.scopusid | 2-s2.0-85077449871 | - |
dc.type.rims | ART | - |
dc.citation.volume | 32 | - |
dc.citation.issue | 2 | - |
dc.citation.beginningpage | 688 | - |
dc.citation.endingpage | 696 | - |
dc.citation.publicationname | CHEMISTRY OF MATERIALS | - |
dc.identifier.doi | 10.1021/acs.chemmater.9b03475 | - |
dc.contributor.localauthor | Yoon, Dong Ki | - |
dc.contributor.nonIdAuthor | McBride, Michael | - |
dc.contributor.nonIdAuthor | Risteen, Bailey | - |
dc.contributor.nonIdAuthor | Zhang, Guoyan | - |
dc.contributor.nonIdAuthor | Khau, Brian V. | - |
dc.contributor.nonIdAuthor | Reichmanis, Elsa | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | LIQUID-CRYSTAL ALIGNMENT | - |
dc.subject.keywordPlus | THIN-FILM TRANSISTORS | - |
dc.subject.keywordPlus | ORGANIC SEMICONDUCTORS | - |
dc.subject.keywordPlus | REGIOREGULAR POLY(3-HEXYLTHIOPHENE) | - |
dc.subject.keywordPlus | CHARGE-TRANSPORT | - |
dc.subject.keywordPlus | LARGE-AREA | - |
dc.subject.keywordPlus | ARTIFICIAL DNA | - |
dc.subject.keywordPlus | ORIENTATION | - |
dc.subject.keywordPlus | DESIGN | - |
dc.subject.keywordPlus | PERFORMANCE | - |
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