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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

Pd-Catalyzed Allylation of Imines to Access alpha-CF3-Substituted alpha-Amino Acid Derivatives

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dc.contributor.authorWinter, Michaelko
dc.contributor.authorKim, Hyunwooko
dc.contributor.authorWaser, Marioko
dc.date.accessioned2019-12-20T07:20:20Z-
dc.date.available2019-12-20T07:20:20Z-
dc.date.created2019-11-18-
dc.date.created2019-11-18-
dc.date.created2019-11-18-
dc.date.created2019-11-18-
dc.date.issued2019-11-
dc.identifier.citationEUROPEAN JOURNAL OF ORGANIC CHEMISTRY, v.2019, no.42, pp.7122 - 7127-
dc.identifier.issn1434-193X-
dc.identifier.urihttp://hdl.handle.net/10203/270075-
dc.description.abstractWe herein report a high yielding protocol for the direct alpha-allylation of easily accessible trifluoropyruvate-derived imines using Pd-catalysis. The reaction gives access to a variety of different alpha-allylated-alpha-CF3-amino acids in a straightforward manner, starting from commercially available trifluoropyruvate. We also provide a proof-of-concept for an enantioselective protocol (up to er = 75:25) by using chiral phosphane ligands.-
dc.languageEnglish-
dc.publisherWILEY-V C H VERLAG GMBH-
dc.titlePd-Catalyzed Allylation of Imines to Access alpha-CF3-Substituted alpha-Amino Acid Derivatives-
dc.typeArticle-
dc.identifier.wosid000494502000001-
dc.identifier.scopusid2-s2.0-85074812826-
dc.type.rimsART-
dc.citation.volume2019-
dc.citation.issue42-
dc.citation.beginningpage7122-
dc.citation.endingpage7127-
dc.citation.publicationnameEUROPEAN JOURNAL OF ORGANIC CHEMISTRY-
dc.identifier.doi10.1002/ejoc.201901272-
dc.contributor.localauthorKim, Hyunwoo-
dc.contributor.nonIdAuthorWinter, Michael-
dc.contributor.nonIdAuthorWaser, Mario-
dc.description.isOpenAccessY-
dc.type.journalArticleArticle-
dc.subject.keywordAuthorAmino acids-
dc.subject.keywordAuthorAllylation-
dc.subject.keywordAuthorUmpolung-
dc.subject.keywordAuthorAsymmetric catalysis-
dc.subject.keywordAuthorTrifluoropyruvate-
dc.subject.keywordPlusASYMMETRIC UMPOLUNG ALLYLATION-
dc.subject.keywordPlusPHASE-TRANSFER-
dc.subject.keywordPlusSTRECKER REACTION-
dc.subject.keywordPlusALLYLIC ALKYLATION-
dc.subject.keywordPlusTRIFLUOROMETHYL-
dc.subject.keywordPlusFLUORINE-
dc.subject.keywordPlusESTER-
dc.subject.keywordPlusCYCLOADDITION-
dc.subject.keywordPlusALKYNYLATION-
dc.subject.keywordPlusGENERATION-
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CH-Journal Papers(저널논문)
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