Ru-Catalyzed Deoxygenative Regioselective C8-H Arylation of Quinoline N-Oxides

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Regioselective C-H functionalization on quinolines is of high interest to lead to value-added products. Herein, we describe the development of Ru-catalyzed deoxygenative regioselective C8 arylation of quinoline N-oxides with arylboronic esters. Mechanistic studies revealed that it proceeds in a tandem process of arylation and then deoxygenation, wherein both steps were found to be catalytic with the ruthenium species.
Publisher
AMER CHEMICAL SOC
Issue Date
2019-10
Language
English
Article Type
Article
Citation

JOURNAL OF ORGANIC CHEMISTRY, v.84, no.20, pp.13150 - 13158

ISSN
0022-3263
DOI
10.1021/acs.joc.9b01548
URI
http://hdl.handle.net/10203/268330
Appears in Collection
CH-Journal Papers(저널논문)
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