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Ligand-Controlled Direct Hydroformylation of Trisubstituted Olefins

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dc.contributor.authorShin, TaeIlko
dc.contributor.authorKim, Hyungsooko
dc.contributor.authorKim, Sungminko
dc.contributor.authorLee, Ansooko
dc.contributor.authorSeo, Min Seobko
dc.contributor.authorChoi, Jonghoonko
dc.contributor.authorKim, Hyungjunko
dc.contributor.authorKim, Hyunwooko
dc.date.accessioned2019-09-03T06:20:45Z-
dc.date.available2019-09-03T06:20:45Z-
dc.date.created2019-09-02-
dc.date.created2019-09-02-
dc.date.created2019-09-02-
dc.date.issued2019-08-
dc.identifier.citationORGANIC LETTERS, v.21, no.15, pp.5789 - 5792-
dc.identifier.issn1523-7060-
dc.identifier.urihttp://hdl.handle.net/10203/266622-
dc.description.abstractThe direct hydroformylation of trisubstituted olefins has been achieved with a combination of a Rh(I) catalyst and a pi-acceptor phosphorus (briphos) ligand. A sterically bulky briphos ligand with a large cone angle that forms a 1:1 complex with Rh(I) is found to be reactive for the hydroformylation of trisubstituted olefins. The aldehyde products were obtained with high diastereoselectivity (>99:1) and regioselectivity (49%-81%).-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.titleLigand-Controlled Direct Hydroformylation of Trisubstituted Olefins-
dc.typeArticle-
dc.identifier.wosid000480371600005-
dc.identifier.scopusid2-s2.0-85067422874-
dc.type.rimsART-
dc.citation.volume21-
dc.citation.issue15-
dc.citation.beginningpage5789-
dc.citation.endingpage5792-
dc.citation.publicationnameORGANIC LETTERS-
dc.identifier.doi10.1021/acs.orglett.9b01639-
dc.contributor.localauthorKim, Hyungjun-
dc.contributor.localauthorKim, Hyunwoo-
dc.contributor.nonIdAuthorKim, Hyungsoo-
dc.description.isOpenAccessN-
dc.type.journalArticleArticle-
dc.subject.keywordPlusRHODIUM-CATALYZED HYDROFORMYLATION-
dc.subject.keywordPlusPHOSPHORAMIDITE BRIPHOS LIGANDS-
dc.subject.keywordPlusREGIOSELECTIVE HYDROFORMYLATION-
dc.subject.keywordPlusSELECTIVE HYDROFORMYLATION-
dc.subject.keywordPlusALCOHOLS-
dc.subject.keywordPlusCOMPLEXES-
dc.subject.keywordPlusPHOSPHINE-
dc.subject.keywordPlusBOND-
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CH-Journal Papers(저널논문)
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