High-throughput synthesis of new Ni(II), Pd(II), and Co(II) catalysts and polymerization of norbornene utilizing the self-made parallel polymerization reactor system

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We report the development of new Ni(II), Pd(II), and Co(II) catalysts containing ligands of pyrazolylpyridine derivatives by combinatorial and high-throughput synthesis technology. Vinyl type polynorbornene was polymerized utilizing the self-made parallel polymerization reactor system. The Ni(II) catalyst 1 has a polymerization activity of 266.7 kg(polymer) . mol(cat)(-1) . h(-1). We introduce a fast way to conduct catalyst synthesis and high-throughput screening for polymerization.
Publisher
WILEY-V C H VERLAG GMBH
Issue Date
2004
Language
English
Article Type
Article; Proceedings Paper
Keywords

VINYL-TYPE POLYMERIZATION; SOLID-PHASE SYNTHESIS; RUTHENIUM(II) COMPLEXES; ENCODING STRATEGIES; LIGANDS; PALLADIUM(II); CHELATE; FAMILY

Citation

MACROMOLECULAR RAPID COMMUNICATIONS, v.25, no.1, pp.302 - 306

ISSN
1022-1336
DOI
10.1002/marc.200300158
URI
http://hdl.handle.net/10203/261545
Appears in Collection
CBE-Journal Papers(저널논문)
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