Computational Analysis of Linker Defective Metal-Organic Frameworks for Membrane Separation Applications

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Intracrystalline defects in metal-organic frameworks (MOFs) are known to have crucial roles in dictating their material properties. In this work, computational simulations were used to induce linker vacancy defects in MOF membranes and to investigate their influence on H-2/CH4 separation. Linker defective structures were created for the 228 candidate MOFs, and their separation performances were compared between the defective and the nondefective structures. Our results show that the existence of linker vacancy defects can lead to significant performance changes in the MOF membranes, and more importantly, the ranking of the best materials can differ with the defects present. This suggests the importance of taking into account the potential for defects when it comes to materials design for various membrane separation applications.
Publisher
AMER CHEMICAL SOC
Issue Date
2019-03
Language
English
Article Type
Article
Citation

LANGMUIR, v.35, no.11, pp.3917 - 3924

ISSN
0743-7463
DOI
10.1021/acs.langmuir.8b04175
URI
http://hdl.handle.net/10203/261025
Appears in Collection
CBE-Journal Papers(저널논문)
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